Boost for Methanol?

New solid catalyst for the direct low-temperature oxidation of methane to methanol.

As a possible energy source for fuel cells or a substitute for gasoline, methanol is increasingly drawing attention beyond its importance as a feedstock for chemical industry. It can be stored much more efficiently and cheaply than hydrogen and could be distributed by way of the existing network of fuelling stations. The disadvantage is the truly complex synthesis of methanol from natural gas via a detour through synthesis gas. One interesting alternative that was pursued and then abandoned is known as the direct low-temperature oxidation of methane to methanol. A team led by Ferdi Schüth at the Max Plank Institute of Coal Research in Mülheim (Germany) and Markus Antonietti at the Max Planck Institute for Colloids and Interfaces in Potsdam-Golm (Germany) has now developed a novel catalyst. As the researchers report in the journal Angewandte Chemie, this could provide a second wind, if not a major breakthrough, for this process.

Selective Low-Temperature Oxidation of Methane to Methanol

The title reaction was achieved on a solid catalyst in a covalent triazine-based framework formed by trimerization of 2,6-dicyanopyridine in a ZnCl₂ melt. The material possesses bipyridine units as coordination sites for platinum. It shows high activity and can be separated easily from the reaction mixture and recycled several times without significant loss of activity.

[Image credit: Angewandte Chemie International Edition, Wiley-VCH]

“The development of catalyst systems for the direct low-temperature oxidation of methane to methanol has been one of the major challenges in catalysis over the last decades,” says Schüth. The problem is that the bonds in methane are very strong and difficult to break. In addition, under the reaction conditions required, methanol has the tendency to react further to form carbon dioxide. The process thus requires not only highly active but also highly selective catalysts.

One breakthrough was the development of a platinum complex by a research group led by Roy Periana. This complex catalyzes the low-temperature oxidation of methane in concentrated sulfuric acid at temperatures around 200 °C to form methyl sulfate - which can be converted into methanol - in good yield and high selectivity. Despite highly promising results, the complex separation and difficult recycling of this dissolved catalyst, among other things, hampered the commercial application of this process. Development proceeded to the pilot-plant stage before being abandoned. “A solid catalyst that can be easily separated could make such a process viable on a small scale, making possible the efficient, decentralized consumption of natural gas,” says Schüth.

The German researchers have now been able to develop such a solid catalyst, whose high reactivity and selectivity, and its outstanding stability through numerous recycling steps, have raised hopes of its industrial implementation. “Our development is based on a recently discovered class of high-performance polymers,” explains Anonietti. Polymerization of a ring-shaped molecule, an aromatic nitrile, results in a network known to chemists as a “covalent triazine-based framework”, abbreviated as CTF. Loading this substance with platinum results in a highly active, easily separated, and recyclable catalyst.

	Further Information and Source:
-	Dr. Regina Palkovits, Prof. Dr. Markus Antonietti, Dr. Pierre Kuhn, Dr. Arne Thomas, Prof. Dr. Ferdi Schüth: Solid Catalysts for the Selective Low-Temperature Oxidation of Methane to Methanol. In: Angewandte Chemie International Edition; Volume 48 Issue 37, Pages 6909 - 6912, Published Online: 4 Aug 2009 DOI: 10.1002/anie.200902009 URL: direct link
-	Ferdi Schüth, Max-Planck-Institut für Kohlenforschung, Germany
-	Source: Angewandte Chemie International Edition, press release 33/2009
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