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Archaeometry - Verlag: Wiley
Archäometrie ist eine internationale Forschungs-Zeitschrift über Anwendung der physikalischen und biologischen Wissenschaften auf Fragestellungen Archäologie und der Kunstgeschichte. Zu den behandelten Themen gehören Datierungsmethoden, Artefakt-Untersuchungen, mathematische Methoden, Techniken der Fernerkundung, Erhaltungstechniken, Umwelt-Rekonstruktion, biologische Anthropologie und Theoretische Archäologie.
Forty-seven window and vessel glasses from the ‘Great Temple’ at Petra (Jordan), dating to the first/second and fourth centuries ce, were analysed by EPMA for major and minor elements. A subset of 29 samples from Petra and 15 samples from Khirbet et-Tannur were additionally analysed for trace elements, using LA–ICP–MS. Six compositional groups were identified on the basis of the presence of decolouring agents. The majority of the glasses derive ultimately from the Levantine coast, but most of the groups show evidence for highly selective recycling. The observed differences between the two sites could be related to different chronological ranges, functions, relative wealth and trade connections.
‘Historical’ DNA obtained from specimens preserved in natural history collections has proven useful for addressing a wide variety of questions, such as the spread of domesticated species or changes in genetic diversity. With the development of high-throughput sequencing techniques, there is an increasing focus on acquiring genetic information encoded by single-copy nuclear DNA from historical DNA extracts. The development of efficient techniques to determine the level of nuclear DNA preservation in candidate specimens is necessary to maximize the data obtained from these analyses. Although current evidence suggests that a sample's mitochondrial DNA preservation predicts its nuclear DNA preservation, we show that the relationships between mitochondrial and nuclear DNA preservation are complex.
Nine representative sherds from the old (14th–16th century) kilns at the Castle of Cafaggiolo in Tuscany have been analysed by means of internal microstratigraphic analyses and micro-Raman spectroscopy and classified as follows: six engobed and glazed fragments, of which three are covered with an opaque white, decorated layer, one is marbleized, and two are engobed. The surface of the two engobed sherds, fragments of unfinished products, indicates that at least two firing processes were used. Two samples show characteristics of Byzantine pottery, and three of them can be classified as Islamic ware or maiolica, whilst the other one displays intermediate characteristics. The variety of ceramic wares indicates the presence of craftsmen with differing expertise, and suggests that part of their work was dedicated to experimentation on new ceramic production techniques.
Eighty-one samples taken from 68 glass beads found in southwestern Poland on sites of the Lusatian culture from the Hallstatt C and Hallstatt D subphases were analysed by EPMA. A subsample of 18 of these were additionally subjected to analysis by means of LA–ICP–MS in order to validate the results obtained by EPMA. Some glass was made using mineral soda and some using plant ash rich in sodium. Both high-magnesium soda–lime glass (HMG) and low-magnesium soda–lime glass (LMG) were identified. A large number of samples are characterized by low MgO content and medium K2O content (LMMK glass), combined with low concentrations of CaO and high Fe2O3 and Al2O3. All the LMMK glass contains numerous silica crystals and inclusions composed of a number of elements (most frequently Cu, Co, Sb, As, Ag, Ni and Fe). The LMMK glass was presumably made in Europe during the Hallstatt C.
In order to answer the age-old question of whether a given pot was manufactured locally or elsewhere, some archaeologists have turned to geoarchaeological or bioarchaeological methods such as diatom analysis to establish potential clay sources. In this paper, we highlight the complexity of diatom analysis and illustrate how diatoms potentially coming from several sources may be introduced at different stages during the ceramic manufacturing process. Finally, we proceed to evaluate the reliability of diatom analysis as an archaeometric measurement for ceramic provenance, concluding that it may have a more limited usefulness within archaeology than its current frequency of use would indicate.
The transfer of advances in chemometrics into archaeometric research opens up a wide range of new application possibilities in this rapidly developing field. Neutron activation analysis (NAA) of ceramic samples from the Banda Traditional Area (west-central Ghana) combined with chemometrics allowed us to establish a link between current and ancient systems of ceramics production in the historic settlements of Kuulo Kataa and Makala Kataa. Principal component analysis (PCA) and the soft independent modelling of class analogy (SIMCA) method were applied to the Das Dores Cruz data set in order to unequivocally determine the geographical origin of the diverse archaeological samples. After global autoscaling pretreatment, PCA analysis showed a clear difference between samples from different locations. The classification models obtained by SIMCA showed a classification ability of 100% and a prediction ability of 97.7%, with a mean sensitivity of 84% and a specificity of 100% for the three categories. The application of SIMCA showed that some NAA variables (elements) were more important than others in terms of geographical classification. With the class models that we obtained, we were able to determine the origin of the ancient remains. SIMCA has proved to be a powerful technique for the class modelling of archaeological data.
The ground penetrating radar (GPR) technique was tested in Pompeii, in an unexplored area where the Roman ruins are partially buried in the volcanic deposits. The method was also combined with time domain reflectometry (TDR) measurements to estimate the dielectric properties of the different volcanic units. In spite of the total thickness of the covering materials and the high signal attenuation measured in some layers, the radar was able to show a detailed image of the volcanic sediments and to locate the manmade structures hidden in the ash deposits. Moreover, the present study shows that the integrated use of GPR and TDR techniques could be successfully employed to evaluate the performance of the radar in specific terrains covering archaeological sites. Since it is unlikely that a large part of Pompeii will ever be excavated, GPR could be successfully used to produce detailed maps of the ruins still hidden in the subsurface, giving archaeologists the possibility of reconstructing the entire urban development of this unique ancient city.
A water absorption analysis was conducted on 103 clay lamp samples to determine whether the fabrics of this pottery type are porous. If so, this would lend further support to the long-standing assumption that lamp makers coated their lighting vessels with slip—not just for decorative purposes, but as a means of preventing oil seepage of the fuel chamber. The samples were excavated at the Red Sea port of Roman Aila (modern Aqaba, Jordan) and belong to 10 different types originating from Arabia, Palestine, Egypt, Tunisia and Gaul. The results of the experiment reveal that clay lamp fabrics are porous, and comparatively more so than a reference group of non-lamp pottery from Pella (Jordan). Petrographic thin-section analysis of select fabrics confirms the presence of pores, cracks and propagating veins indicative of thermal stress resulting from repeated lamp use. Meandering veins identified in a nozzle fragment were created by the diffusion of vapours, probably originating from the burning lamp oil itself. Ancient lamp makers understood that, given its direct exposure to the extreme temperature of the flame, the nozzle was particularly vulnerable to breakage as a result of thermal shock. A porous lamp fabric, however, helped limit crack propagation, allowing the nozzle and the lamp body to expand and contract to avoid breakage.
The reliable identification of fakes consisting of bronze often presents problems, because traditional methods such as stylistic studies, optical microscopy, chemical analysis or X-ray diffraction of the corrosion may not be conclusive. We present a method that is based on the comparison of the tin isotope ratios 122Sn/116Sn and 117Sn/119Sn in the metal and in the adherent corrosion layer. An artificial patina is usually generated within a short time period. It has been observed that such a procedure leads to a depletion of the light tin isotopes in the corrosion layer, while in naturally corroded authentic archaeological objects no isotopic fractionation has been detected. The method has also been applied to archaeological objects and it could be confirmed, among other examples, that the famous ‘Sky Disc of Nebra’ is authentic.
The microstructures of porcelain and stoneware bodies from north and south China, spanning the period from the Tang to the Ming dynasty (7th–17th centuries ad), were examined in polished sections in a scanning electron microscope (SEM) after etching the sections with hydrofluoric acid (HF). Mullite, present as fine, mainly elongated crystals, is the dominant crystalline phase observed. The bulk chemical compositions of the bodies are determined by energy-dispersive spectrometry in the SEM, and the relative amounts of mullite and quartz present in the different ceramics are estimated from X-ray diffraction measurements. Mullite formed from areas of kaolinitic clay, mica particles and feldspar particles is distinguished through a combination of the arrangement of the mullite crystals, and the associated SiO2/Al2O3 wt% concentration ratios. It is shown that very different microstructures are observed in ceramic bodies produced using kaolinitic clay from north China (Ding porcelain and Jun stoneware), porcelain stone from south China (qingbai and underglaze blue porcelain and Longquan stoneware), and stoneware clays from south China (Yue and Guan stonewares). Therefore, SEM examination of HF-etched, polished sections of the bodies of high-refractory ceramics has considerable potential for investigating the raw materials used in their production.
The measured chemical composition of archaeological ceramics can result from a variety of geological, cultural and taphonomic factors. In the present study, we evaluate the likelihood that elevated barium concentrations in ceramics from the archaeological site of Wom/Aiser, located on the northern coast of Papua New Guinea, result from post-depositional enrichment. Using time-of-flight–laser ablation–inductively coupled plasma–mass spectrometry, we mapped chemical compositional profiles across cut sections of ceramic sherds from four archaeological sites, all previously chemically characterized. We identify the formation of pronounced concentration gradients in samples from Wom/Aiser relative to sherds with low barium concentrations, consistent with post-burial uptake.
The crystallite size, microstrain, stacking disorder and moganite content of flint and other chert raw materials were studied by X-ray powder diffraction profile analysis. The broadening of the X-ray reflections of all microfibrous quartz varieties is due to both anisotropic small crystallite size and anisotropic microstrain. The microstructure varies for samples of different origin. The moganite content and the number of structural defects are higher in flint than in older chert and petrified wood. The X-ray diffraction pattern of the cortex of flint differs from that of the core material, whereas those of the patina and the unweathered interior of the rocks do not.
This analytical study aims to investigate ancient Egyptian black-patinated copper alloys. The study group was selected from the collections of the Egyptian Museum in Cairo and from the Faculty of Archaeology Museum in Cairo University. Examination and analysis were undertaken using optical microscopy (OM), scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDX), X-ray diffractometry (XRD), X-ray fluorescence analysis (XRF) and Fourier transform infrared spectroscopy (FTIR). The analysis results indicated that the black patina contained mainly tenorite (CuO). The study presents evidence of thermal patination and animal glue coating.
An archaeometric study of all the Roman millstones preserved today in the National Archaeological Museum of Aquileia, the ancient capital of the X Regio Augustea –‘Venetia et Histria’ located on the Friuli plain (northeastern Italy), has been recently envisaged to define their geological–geographical provenance. We present here the results of the first step of the research, which is aimed at characterizing all of the definitely allochthonous lithologies. In order to carry out petrography on thin-section and geochemical analyses, 10 small samples were picked out directly from Pompeian-style millstones (catilli and/or metae) and rotary querns. Five different lithologies originating in various Italian regions were recognized: eight samples consist of pale- and dark-grey lavas from the Venetian Volcanic Province, Vulsini Volcanic District (Latium), Etna Volcano and Pantelleria island (Sicily), whereas two samples were shown to be made of green garnet-bearing schists (pietra ollare) from the Western Italian Alps. The presence of Alpine pietra ollare in northeastern Italy, used to produce pots and food containers, was established for numerous classical findings at Roman and Middle Age sites, but the analysed items represent the first evidence for the utilization of this kind of stone to produce mills during the Roman epoch.
This work investigates the decayed decoration of the ‘Vergine del Carmelo’ chapel, with a particular interest in the residual gildings. Samples of the finishing layers were examined by VIS-UV optical microscopy and scanning electron microscopy coupled with EDX spectrometry, in order to evaluate the unusual degradation phenomena. Mineralogical composition of the stucco substrate was characterized by X-ray diffraction (XRD) and FTIR spectroscopy. The results showed the unexpected presence of a thick layer of brass flakes, applied without any binder, used as a substitute for the damaged original gold leaf, and highlighting a very uncommon selective corrosion process of the brass.
An archaeometric study was performed on 33 medieval glass samples from Rocca di Asolo (northern Italy), in order to study the raw materials employed in their production, identify analogies with medieval glass from the Mediterranean area and possible relationships between chemical composition and type and/or production technique, contextualize the various phases of the site and extend data on Italian medieval glass. The samples are soda–lime–silica in composition, with natron as flux for early medieval glasses and soda ash for the high and late medieval ones. Compositional groups were identified, consistent with the major compositional groups identified in the western Mediterranean during the first millennium ad. In particular, Asolo natron glass is consistent with the HIMT group and recycled Roman glass; soda ash glass was produced with the same type of flux (Levantine ash) but a different silica source (siliceous pebbles, and more or less pure sand). Cobalt was the colouring agent used to obtain blue glass; analytical data indicate that at least two different sources of Co were exploited during the late medieval period. Some data, analytical and historical, suggest a Venetian provenance for the high/late medieval glass and a relationship between type of object (beaker or bottle) and chemical composition.
The transformation of yellow goethite into red hematite by heating has long been assumed for Palaeolithic red artefacts excavated close to fireplaces. However, this transformation is extremely rare. Using SEM–FEG–EDX, PIXE–PIGE, TEM and ?XRD, we characterized the mineralogical and chemical compositions of four microsamples of colouring materials from the Mousterian layer B in the es-Skhul rock-shelter, from about 100 kya ago. For some colouring materials, the Mousterian people of es-Skhul chose to gather remote yellow lumps for heating. Their significant transport distance provides evidence of the possible high cultural value of these colouring materials for transformation into red pigments.
Flint was one of the most widely employed raw materials for artefact manufacture in Denmark and Sweden during the Stone Age, and it continued to be used during subsequent periods. Prehistoric flint mining and lithic manufacturing studies in these countries have attracted considerable attention, but there have been no recent attempts to chemically characterize the geological source materials. This paper builds on a pilot study (Hughes et al. 2010) and uses energy-dispersive X-ray fluorescence (EDXRF) analysis to determine quantitative composition estimates for nine major, minor and certain trace elements in seven archaeologically significant flint sources in Denmark and Sweden, along with new data on a number of other sources of prehistoric significance. These data provide a geochemical foundation for ongoing research devoted to determining contrasts and continuities in the time and space utilization of flint sources in Scandinavian prehistory.
The helium pycnometer allows us to measure the cell-wall density of dry woods and the basic density of wood samples soaked with water and/or a consolidant solution if a non-volatile solvent is used. These parameters were correlated to the porosity, which for degraded waterlogged wood is related to the maximum water content. Moreover, this has revealed the possibility of investigating, by means of accurate cell-wall density determination, the efficacy of several consolidants in the treatment of waterlogged woods.
During the Classic Period, Teotihuacan was an economic centre of central Mexico, but little is known about the development of this system. This paper presents a pilot study in multi-method analysis of Formative Period (1500/1400 bc–ad 150) ceramics from the Teotihuacan Valley. Pottery was characterized by instrumental neutron activation analysis, laser ablation inductively coupled plasma mass spectrometry, thermal ionization mass spectrometry and petrography. It appears that most pottery was made from local raw materials that differ from later Postclassic materials. Some inter-village interaction is suggested by stylistic choices, and one settlement had a group of ceramics made from unequivocally distinct raw materials. The study demonstrates how complementary methods can be used to draw greater anthropological meaning from compositional differences.
The results of the first elemental and structural physicochemical analyses (SEM–EDX, TXRF, XRD, FTIR, GC and EDXRF) of Early Neolithic red pigment samples from the region of Valencia confirm one of the earliest uses of cinnabar (HgS) in Spain (5300 to 5000 cal bc). They also inform on the storage of massive quantities of hematite and the development of specific technologies of hematite-based paint production and use. The samples were recovered at the three most significant Early Neolithic sites of the Mediterranean coast of Spain: Cova de l'Or (Beniarrés, Alacant), Cova de la Sarsa (Bocairent, Valencia) and Cova Fosca (Vall d'Ebo, Valencia), which together have provided the most important European collection of Cardial ceramic ware (chronoculturally diagnostic of the Early Neolithic).
Identification of the painting technique adopted by an artist is often debated in studies on the characterization, restoration and conservation of mural paintings. However, objective criteria to identify the two main lime-based painting techniques, fresco and lime-paint, have not yet been systematically verified on replicas. Replicas were painted following both fresco and lime-painting techniques. A comparison of microstratigraphic sequences and distribution of chemical elements reveals systematic differences between the two techniques, providing objective distinguishing criteria. Samples from the Abbey of Chiaravalle (Milan, Italy) and Pompeii were also analysed, and the results were compared with experimental data to validate the recommended criteria.
This paper is aimed at defining the artistic technique performed by the outstanding artist Isidoro Bianchi for the Baroque stucco decorations in the church of Santa Maria dei Ghirli (Campione d'Italia, Italy). Samples of stucco were examined by means of optical microscopy, scanning electron microscopy with a microprobe, X-ray powder diffraction, Fourier transform infrared spectroscopy, gas chromatography–mass spectrometry and laser ablation mass spectrometry equipped with plasma source spectrometry. On the basis of the results obtained, art historians have made new hypotheses on the biography of the artist and on the historical location of his birthplace.
Despite predictions in the 1980s that electron microprobe analysis (EMPA) would become a popular technique for obsidian sourcing, few studies have used it with this goal, and most of them are now outdated and unrepresentative of modern EMPA. For example, Merrick and Brown (1984) recorded their data on punch cards. Furthermore, these studies destructively prepared artefacts for analysis. The research at hand endeavoured: (1) to establish the modern capabilities of EMPA for obsidian sourcing; and (2) to develop and evaluate procedures for non-destructive artefact analysis. Issues such as diagenetic effects and compatibility with NAA and XRF data were also investigated.
Koji pottery is a glazed ceramic art used widely for figurines. In early Taiwan, it was employed in temple construction for decorative purposes. Ye Wang (1826–87) is the first historically documented Koji artist of Taiwan and also the most prominent Koji pottery artist, noted for his modelling and glazing skills. Unfortunately, his unique technique was lost following his death in 1887. In order to provide vital information for ongoing conservation work on Koji pottery, this study analysed the physical and chemical characteristics of Ye Wang's gem-blue glaze, to discover the glaze formula. DSC combined with the two-thirds rule revealed that the firing temperature of Ye Wang's works of art was most probably around 878–923°C. EPMA revealed that the gem-blue glaze has high alkali levels, and belongs to the PbO–K2O–B2O3–Na2O–SiO2 system, deriving its unique colour from copper, iron, manganese and cobalt. This study found high potassium levels in the gem-blue glaze, which are generally a characteristic of traditional Chinese glazes. In addition, a unique discovery of boron, commonly used in famille rose, was also identified in the glaze. By comparing spectra of historical and reconstructed glazes and adjusting the proportion of chromophoric elements, this study found a glazing formula with colours close to those of Ye Wang's gem-blue glaze.
Mortars were among the first materials used for construction purposes, even from prehistoric times. Their systematic study reveals that they often contained inclusions, which were introduced with the main constituents or added as improvers of mortars' properties. The present study focuses on recording the types of inclusions found in more than 1000 mortar samples of different types (structural, renders and floor mosaic substrates), taken from various monuments of Greece. This extensive study proves that inclusions occur in all types of mortars of all periods and can be distinguished into two categories: those that are added deliberately to mortars to meet specific needs of improvement of their final properties, such as fibrous materials (wood chips, straw); and inclusions that are incorporated into the mass as impurities in the raw materials (lime and clay lumps, shells and probably charcoal particles).
Ancient glass vessel fragments belonging to the seventh to ninth centuries ad, from the Ko Kho Khao, Laem Pho and Khuan Lukpad sites in southern Thailand, were studied. The glass vessel fragment samples are a collection belonging to the Department of Archaeology, the 15th Regional Office of Fine Arts of Thailand. The chemical compositions of the glasses were analysed using a modified portable energy-dispersive X-ray fluorescence spectrometer (OURSTEX 100FA-II) by the introduction of a MOXTEK® AP3.3 polymer window (5 mm2?) to the KETEK silicon drift detector for the measurement of light elements. The non-destructive analysis was performed at the National Museum, Phuket, in Thailand. It is shown that the glass chemical compositions belong to mineral and plant-ash based soda–lime–silicate glass. The origins of the glass artefacts are discussed in terms of raw materials and glass decoration, and compared with previously reported similar typological glasses from sites in the port city of R?ya and the Monastery of Wadi al-Tur in Egypt.
The geological sources of obsidian in the Red Sea region provide the raw material used for the production of obsidian artefacts found in prehistoric sites on both sides of the Red Sea, as far afield as Egypt, the Persian Gulf and Mesopotamia. This paper presents the chemical characterization of five obsidian geological samples and 20 prehistoric artefacts from a systematically excavated Neolithic settlement in highland Yemen. The major element concentrations were determined by SEM–EDS analysis and the trace element concentrations were analysed by the LA–ICP–MS method, an almost non-destructive technique capable of chemically characterizing the volcanic glass. A comparison of archaeological and geological determinations allows the provenance of the obsidian used for the Neolithic artefacts to be traced to definite sources in the volcanic district of the central Yemen Plateau.
Iron raw materials provide a privileged source of information for the reconstruction of metallurgical techniques and the circulation of iron products. An interdisciplinary approach, combining archaeological and archaeometrical studies of the exemplars known from the French Iron Age, has been undertaken. This enables a new typological classification to be produced that demonstrates a correlation between morphological and structural properties. Through comparison with chronological data, it is possible to propose a reconstruction of the organization of production according to three main periods, which are characterized by the circulation of different qualities of iron and by diverse levels of artisanal specialization.
Pompeii is an important temporal reference in the study of Roman ceramics, yet until now the origins of red slip tableware or sigillata found in the city have largely been classified by visual evaluations of the pottery. This investigation employs petrographic and elemental analyses to establish the provenance of sigillata found in two pre–ad 79 contexts of Pompeii. In contrast to previous studies, the results suggest that pottery workshops in the vicinity of Somma-Vesuvius played a vital role in the supply of sigillata to the city.
The Early Bronze Age necropolis of Singen (Hohentwiel), located near Lake Constance, represents a population from a period of technological transition in southwestern Germany. The site contains several graves with metal artefacts that originated in other parts of Central and Western Europe, and therefore these could be interpreted as being the graves of non-local individuals. The purpose of this study was to investigate this possibility through the application of isotopic analysis. The ratios of strontium and oxygen isotopes in human enamel reflect the geological origin of food and drinking water consumed during enamel formation in early life stages. Additionally, the ratio of sulphur isotopes from bone collagen reflects the origin of foods consumed during the last 10–20 years of life of an adult individual. We used these three isotope systems to attempt to identify local and non-local individuals at the site. We found that the isotope ratios of Sr, O and S of the humans were relatively homogeneous and generally correspond to the isotope signature of the local geology, climate and environment. We conclude that the sampled population is of local origin and does not show patterns of individual mobility, even though there is evidence for long-distance trade and exchange of the metal artefacts at this site.
In west-central Neuquén Province, Argentina, in the area around Estancia Llamuco, west of Zapala, south of Las Lajas and north-east of Lago Aluminé, there are multiple primary and secondary sources of obsidian. Primary sources occur within the south-east extension of the Plio-Quaternary volcanic chain that runs from Copahue volcano through Pino Hachado. Secondary sources include river-bed gravels within the valleys of Arroyo Cochicó Grande and Río Kilca as far south as where this river joins with Río Aluminé, and the Quaternary fluvial–glacial sediments cut by the valley of Río Covunco as far east as Portada Covunco. Visually variable obsidians from these two secondary sources include homogeneous black and grey-translucent types, porphyritic and banded types, and an abundant quantity of oxidized red and black obsidian. However, all these visually distinct obsidians have similar and unique chemistry, with Ba between 220 and 340 ppm, different from any other obsidians previously reported from Neuquén, which all have Ba > 500 ppm, as do obsidians from sources to the north in Mendoza and to the west in Chile. This chemical distinctive obsidian has been exploited and transported over a wide area, beginning prior to 4000 bp, and occurs in local archaeological sites, as well as sites ? 300 km to the north-east in La Pampa Province, ?430 km to the south in Chubut Province, and >75 km to the west across the Andean drainage divide in Chile.
Wood preserved in the corrosion layer of two early medieval iron objects was examined using X-ray tomography. A state-of-the art multi-resolution X-ray tomography set-up (http://www.ugct.ugent.be) provided virtual cross-sections of the archaeological wood samples at sub-micron resolution. These were compared with scans of samples of similar modern wood. These scans demonstrate the power of sub-micron X-ray tomography for wood identification, although the process of mineralization pushes this technique to its limits. Furthermore, this technique facilitated appraisal of the mineral content of the archaeological wood, which is useful in selecting the most appropriate strategy for the (preventative) conservation of the archaeological object.
Lead isotope ratios in ore bodies and magmatic rocks depend in a complex way on several a priori independent parameters, including the geological age of the tectonic province in which the ores and magmas formed and its U/Pb (?) and Th/U (?) ratios, two very sensitive parameters characteristic of metal sources. All these parameters are entangled in hard-to-read Pb isotopic ratios. With respect to the commonly used fingerprinting techniques, which rely on the comparison of raw isotope ratios, the main motivation for the present work is to provide a method for making geologically and geochemically educated guesses about metal provenance even in the absence of isotopic data on reference ores. It shows how to unscramble a geological model age and ? and ? information from isotopic measurements. This approach brings to light a new organization of the Pb isotope database and an untapped wealth of information that can be used for provenance studies and other archaeometric purposes. We provide expressions with which to calculate these parameters and, using literature data, demonstrate how Pb isotopes in ores and magmas define clear zones in the silver-rich provinces of the Central Andes. We further show how the geological model age and ? and ? values fingerprint production areas in 16th–18th century silver coins minted in Mexico and South America. Finally, we use Pb isotopes to illustrate how the Reconquista of the Emirate of Granada (1482–91) and the seizure of the Betic silver mines are reflected in the silver coins of the Catholic Monarchs.
This paper presents a visualization system based on metric data to manage and disseminate archaeological information on the Internet. We describe the integration of two different types of sensors: laser scanning and close-range photogrammetry. How we created an automatic and hierarchical approach based on processing and matching the images coming from a digital camera and a terrestrial laser scanner is also shown. This development has created a visualization system combining spherical photographs and georeferences for graphical and numerical data acquired by the sensors. The case study where we have applied this method is the Palaeolithic rock art of the Llonín Cave (Asturias, Spain), which has been declared a World Heritage Site by UNESCO and has restricted public access. Our results demonstrate that this tool integrates data, metadata, services and information, which simplifies the location, identification, selection and management of archaeological information.
Here we show the results of a study concerning a small group of shaft-hole axes found in northeastern Italy, made from amphibole-rich metabasites, fine-grained and free of phenoblasts. The main mineral phases are amphibole, ranging from actinolite to hornblende, and plagioclase (An10–15 and An70–77). The amphiboles generally show a needle shape and are often radially arranged. Quartz is present in thin veinlets, while ilmenite is widespread in small patches. The petrographic and geochemical features suggest that the axes originate from the southern thermal aureole of Tanvald granite in northern Bohemia. In accordance with this provenance, the typology of the tools shows similarities with the perforated shoe-last axes spread across Central Europe during the fifth millennium bc and made from similar raw material. For the first time, these axes give evidence of long-distance (about 800 km) contacts between northeastern Italy and Central Europe during the Neolithic.
The Xicun kiln in Guangdong Province was a famous porcelain kiln in the Song Dynasty of China, and for years there has been controversy over the provenance of Xixun Qingbai wares. This paper analyses Qingbai samples from the Xicun, Hutian (Jingdezhen) and Chaozhou (Guangdong Province) kilns by laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) and energy-dispersive X-ray fluorescence probe (EDXRF). The analytical results indicate that wares with a thin body excavated from the Xicun kiln site were produced in the Hutian kiln, and wares with a thick body were locally fired in Xicun; the contents of trace elements (V, Rb, Ba, Ta, Pb and Th) and the Nb/Ta ratio can be used to discriminate the products from the Xicun and Chaozhou kilns.
In the cruciform gallery of Angkor Wat in Cambodia, red, orange, white and black pigments were widely painted on the surfaces of pillars, walls and friezes. The application sequence of the pigments is different from area to area. The following substances were confirmed from the pigments: hematite (laterite), minium, calcium oxalate hydrates (whewellite and weddellite), Pb–Cl compounds (cotunnite, laurionite and blixite), calcium phosphates (whitlockite), gypsum, hydrocerussite, calcite, anglesite, lead dioxide, azurite and carbon black. The orange pigment (minium) underlies the red pigment (hematite). The former may have been applied at the time of the foundation (the Angkor Wat style period), and the latter in the Bayon style period or later, but mainly before the early 17th century of the current era.
For a long time now, historians have considered the way across the Col de Clapier as the most likely invasion route of Hannibal's army across the Alps. Mahaney et al. challenge this view by introducing a two-tier rockfall into the discussion, which they believe is mentioned in the ancient texts and has gone unnoticed by modern scholars. Since a deposit of this kind can only be found at the Col de la Traversette—and there alone—Hannibal's crossing of the Alps, so they reason, must have followed this alternative route. However, a critical reassessment of the ancient texts and a closer look at the geomorphological situation clearly show that this interpretation is unwarranted.
The degradation mechanisms of glass in a buried context result in surfaces that have been depleted in various elements. The stability of the glass is primarily affected by the burial environment and the glass composition. However, in all archaeological glasses, the corroded layer that is formed on the surface tends to be low in alkalis, high in silica and lacking in cohesion. The extent to which the material has degraded, along with the physical nature of the corrosion, has a profound effect upon a wide range of factors affecting the stability of artefacts, as well as the choice of conservation techniques to be employed. This study has a number of objectives: determination of the morphology of the surface of the leached layer in glasses of two different compositions with different surface finishes; examination of the transition between the corroded material and the unaffected substrate; and investigation of concentration profile of different elements within the surface layers, as a function of depth. The study uses two glasses, fabricated under laboratory conditions, to replicate two common glass types found in the historical environment; a soda–lime–silica glass typical of those found in the Roman period throughout the Mediterranean and northwestern Europe, and high-lime–potash glasses typical of those of Western Europe in the late medieval period. Three different surfaces have been prepared to mimic alternative manufacturing techniques such as blown, cast and ground surfaces for each composition. The glasses have been corroded under controlled laboratory conditions to replicate the buried environment. Imaging and chemical information is obtained using SEM–EDX and morphological information using IFM to produce 3-D mapping from topographical surfaces.
An archaeometallurgical analysis is presented of 14 bronze artefacts retrieved from an Early Hellenistic–period farmstead in controlled archaeological excavations at Rishon Le-Zion, Israel, and dated to the first quarter of the third century bce according to coins and pottery vessels. The bronze assemblage includes a needle, pins, spatulas and fibulas. The aims of the research are to determine the composition, microstructure and manufacturing process of these artefacts, and to discover their place of production. This will provide a better understanding of Hellenistic technological abilities and material culture. The examination included optical microscopy, microhardness, SEM including EDS, and XRD. The results show that the collection consists of Cu–Sn binary alloys, with evidence for a controlled alloying process and the absence of recycling. Furthermore, the microstructure of the objects indicates that all artefacts were produced by a cold-working process. Moreover, the manufacturing process of the rectangular cross-section fibulas included sophisticated joining techniques of copper and iron.
This study presents the first ever lead isotope ratio data for copper ore samples (malachite and azurite) from the Sierra El Aramo (Asturias, northwestern Spain). The aim of this study was to supplement information in the existing reference database on the lead isotopic composition of Spanish ores. The Sierra El Aramo is particularly important because, while no data for the Asturian ores have been published so far, this northern province of Spain has played a significant role in terms of copper exploitation and metallurgy since the Copper Age.
Archaeological evidence for wind musical instruments made by modern humans has been well established from the Upper Palaeolithic in Europe. Musical instruments evidently made by Neanderthals have not been found so far. The most controversial object is a juvenile cave bear femur with two complete holes, found in 1995 in the Middle Palaeolithic layers of the Cave Divje babe I, Slovenia. The bone was interpreted as a possible Neanderthal ‘flute’, but some scholars have firmly rejected this hypothesis on the basis of taphonomic observations, suggesting a carnivore origin for the holes. Here, we show the results of X-ray computed micro-tomography (mCT) performed on the Divje babe I ‘flute’. Our analyses demonstrate that there were originally four holes, possibly made with pointed stones and bone tools. Most surface modifications near the holes, previously interpreted as effects of carnivore gnawing, are post-depositional marks. Furthermore, a thin layer has been removed around one of the complete holes, producing a flat surface, possibly to facilitate perforation. The new data show that a Neanderthal manufacture of the object cannot be ruled out.
To improve the methods used to study prehistoric cremation rituals, cremation urns from the Danish Late Bronze Age were examined using computed tomography and computed radiography (digital X-ray). During micro-excavation, the digital images were used as a registration tool. Our results suggest that osteological ageing and sexing are more accurate when combining CT images with excavated remains. Digital volume rendering further enables a compromised estimation of the original cremation weight. Micro-excavation is clearly a primary cause of bone fragmentation. Cremated remains affected by lower cremation intensity show markedly poorer preservation and recovery than do white calcined fragments. Thus post-excavation estimations of cremation intensity are systematically biased.
Analytical investigations of fragmented Meissen porcelains well dated to between 1725 and 1763 have been carried out using SEM–EDS. The aim of the analysis was to characterize elements in bodies, glazes and overglaze enamels in order to create a baseline data set of materials used in the manufacture of porcelain at the Meissen factory, Saxony, during the 18th century. Analyses indicate body and glaze compositions to be consistent with a post c.1720–30 date, when a change from a lime-rich flux to a potassium-rich flux is documented to have occurred. Overglaze enamel compositions are shown to be consistent with contemporary accounts of enamel preparations at Meissen. Overglaze enamel compositions show that mixtures of pigments, in addition to documented enamel 18th-century preparations, were in use at Meissen between c. 1725 and 1763.
Brick samples from nine archaeological sites representing seven contemporary medieval settlements in Békés County (SE Hungary) were analysed by quantitative X-ray powder diffraction, optical microscopic, scanning electron microscopic and coupled thermal analytical – evolved gas analytical methods. The aims of this study were to give a mineralogical–petrographical characterization of the brick samples, to gain possible information on the raw clay and the admixed materials, and to determine the firing techniques applied in medieval southeastern Hungary. The mineralogical composition of the samples suggests that the locally extracted clay was mixed with fluvial sand and wheat (Triticum monococcum L.) chaff. The moulded bricks were fired in clamps. The different degrees of calcite consumption suggest that the firing temperature ranged from ?750°C to ?950°C. Moreover, the well-developed reaction coronas on calcite grains indicate long firing times, lasting perhaps several days.
This comment concerns an ‘absolutist’ perspective on the superiority of mineralogical analysis over chemical analysis for the determination of ceramic provenance. This point of view has appeared in the literature in recent years, but it has not been justified and is not justifiable. Mineralogy and chemistry are complementary. They measure different things and are best used in combination to generate secure, geographically specific ceramic source assignments.
Fossilized resin, or amber, has been examined from 120 worldwide sources by 1D and 2D proton magnetic resonance spectroscopy in solution. These spectra fall into five categories, corresponding to the classes already established by mass spectrometry and carbon-13 magnetic resonance spectroscopy. The wide availability of this technique provides a straightforward method to classify amber rapidly and inexpensively.
Three different historical mortars, one from the 18th–19th centuries and two from the 12th century, were crushed and sieved to give eight fractions between less than 0.063 mm and 4 mm for each sample. Each fraction was chemically analysed for the amount of calcium carbonate binder, using the reactions with HCl and EDTA and by means of atomic absorption spectroscopy. The samples were also characterized by X-ray diffraction (XRD) and by low-temperature nitrogen adsorption isotherms. The limitations and advantages of each of the various methodologies for the determination of the binder are discussed. Reactions with HCl and XRD were shown to be the methods that gave the more coherent results.
In Tunisia, the largest amphitheatre (known as the Coliseum) at Thysdrus (El Djem), with some parts of the second amphitheatre, and the Thapsus amphitheatre have been built with squared stone blocks (opus quadratum). The petrographic and geotechnical analyses of the samples taken from the amphitheatre blocks show that these blocks belong to the Tyrrhenian and to the Mio-Pliocene age. Ancient quarries have been found on the Tyrrhenian dune line between Hiboun and Al Alya, at a distance of 30 km from Thysdrus, from which the Tyrrhenian blocks have been extracted. Concerning the Mio-Pliocene blocks, they have most likely been cut from just one ancient quarry found in the hill of Ksour Essaf. The height of almost all of the measured blocks from the Thysdrus Coliseum is equal to the Punic cubit used at Carthage (50 cm), and the height of the measured blocks from the Thapsus amphitheatre is also equal to the Punic cubit (50 cm), or very close to the Roman cubit (45 cm).
The lack of robust chronological frameworks for pre-Columbian archaeology in the Caribbean limits the interpretive potential of ongoing studies of inter-site and inter-island interaction. This paper reviews the dating of 28 wood and shell artefacts from sites in northern Cuba in an attempt to date pre-Columbian activity in the region and develop dating methodologies for the study of pre-Columbian interaction in the Caribbean. This research compares dates from wood and shell artefacts from the waterlogged site of Los Buchillones in north-central Cuba with dates from shell artefacts from sites on eight islands in the Sabana–Camaguey archipelago in the Bahama Channel. In addition to providing a chronological framework based on absolute dates for pre-Columbian activity in northern Cuba, this paper also considers the methodological issues of using shell for dating pre-Columbian activity in the Caribbean.
Intra-tooth sequential analysis of enamel ?18O is currently used to investigate birth seasonality in past animal populations, offering new insights into seasonal availability of animal resources, herd management and seasonality of site occupation. Reference data sets are still required to address two major difficulties: (1) that inter-individual variability in the record of the seasonal cycle is affected by tooth size; and (2) that the season of birth cannot be directly estimated from the timing of tooth growth, because of a delay in enamel mineralization. We present a data set acquired on the lower second molar of 10 modern sheep from Rousay (Orkney) born within a few weeks of each other in April/May and submitted to the same environmental conditions until death. All sheep have recorded a sinusoidal pattern of ?18O variation spanning approximately a year. From the difference between the expected and the measured time sequence, the delay of enamel mineralization is estimated to be 5–6 months. The data set is then described using a model mainly based on a cosine function. The period, corresponding to the length of the M2 crown formed over a year, averaged 35.8 mm. A very slight variation of tooth growth rate with time and no attenuation of the isotopic signal towards the cervical margin of the crown could be detected in this data set. The lowest ?18O values, corresponding to the sheep's first winter, were tracked at a distance from the enamel/root junction that varied between 23.0 and 30.3 mm (xmin mean = 27.6 mm); the highest ?18O values, corresponding to the sheep's second summer, were between 6.3 and 11.6 mm (xmax mean = 9.9 mm). Most of the variability can be attributed to tooth size. When normalized on the period, xmin and xmax are 0.28 (± 0.05) and 0.78 (± 0.05) on average, meaning that the Rousay sheep have recorded the minimum and maximum ?18O values on average at 78% and 28%, respectively, of the end of the periodic cycle recorded in the second molar.
The prototype of a relational database for archaeological ceramics is presented. At this stage, the ceraDAT database contains the elemental compositions of several thousand ceramic artefacts from the Eastern Mediterranean, analysed by neutron activation analysis (NAA) at different laboratories. The data have been calibrated on the basis of the analytical routine and can be accessed via a web application. Apart from the elemental compositions, the database contains reference patterns of specific sites, metadata concerning archaeological information, the geographical distribution, literature references and former statistical evaluations. Due to the database design, the structure can be extended in future towards petrographical and mineralogical information.
A total of 22 samples were taken both from plasters still in situ and from collapsed material recovered by French, Italian and Moroccan teams at the Roman settlement of Thamusida (Rabat, Morocco). The sample characterization was obtained using optical microscopy, scanning electron microscopy, image analysis and Raman micro-spectroscopy. Plaster aggregate was made using a mixture of sands and clays that outcrop nearby, while lime was probably produced using the local limestone crust, as was further verified for the mortars. The plasters from the bath complexes (public buildings) and the Temple à trois cellae (sacred building) were very poorly made, while those from areas VII and XX (private buildings) indicated the involvement of more expert masons. The pigments used were cinnabar, red ochre, yellow ochre, Egyptian blue, green earth, chalk white and carbon black. The overall manufacture was of low quality, and hence perfectly comparable to that observed in other Roman Provinces. With respect to Italy and to other Mediterranean Roman sites, Thamusida fits well within an aesthetic and technical koinè that differentiates sites of the Italian peninsula from those in the Provinces.
Twenty-six tesserae (red, orange, yellow, light amber, green, blue and white) from the balneum of the villa at Faragola (Ascoli Satriano, Foggia) have been examined by colorimetry, ICP–MS, ICP–OES and SEM–EDS. Different types of calcareous sands have been used as the source of silica (network former), also providing the stabilizing agent. A natron-type soda source served as the network modifier; however, the use of a sodium-rich plant ash and the recycling process have been hypothesized for the production of two tesserae (FT 1 red and FT 3 orange). The colouring and opacifying agents were Cu oxide (cuprite, orange), metallic copper (red), Pb antimonates (yellow), Ca antimonates (white), a mixture of copper (Cu2+) and Pb antimonates (green), a mixture of cobalt (Co2+) or copper (Cu2+) and Ca antimonates (blue). The light amber tesserae should owe their colour to iron (Fe3+) alone or associated with sulphide (S2?) and Ca antimonates. It is likely that the Faragola tesserae were locally produced in a secondary glass workshop.
Absolute intensity determinations using the Coe variant of the Thellier method have been carried out on some selected pottery fragments collected in the wetlands of the lower Paraná (Pampean region, Argentina) in order to construct the first archaeointensity master curve for South America. Associated radiometric ages range between 1640 ± 70 and 730 ± 70 bp. Twenty-one samples (five fragments) out of 46 studied (eight fragments) provided successful absolute intensity determinations. The fragment-mean archaeointensity values obtained in this study range from 21.9 ± 2.3 to 42.6 ± 5.4 ?T, with corresponding virtual axial dipole moments (VADMs) ranging from 4.0 ± 0.5 to 8.1 ± 1.0 x 1022Am2. This corresponds to a mean VADM of (6.4 ± 1.8) × 1022 Am2. The synthetic record retrieved from southern Argentina and Brazil consists of 17 mean archaeointensities distributed between approximately ad 700 and ad 1700. The data set shows several distinct periods of fluctuations of quite large intensity. However, most data are concentrated into a relatively narrow time period from ad 950 to ad 1300. Three general features may be detected: the time intervals from about ad 950 to 1130 and 1350 to 1480 are characterized by quite monotonic increases of geomagnetic intensity, while some decrease is observed from ad 1150 to 1280. These variations may be speculatively correlated to climate changes over multi-decadal time scales. Important differences are observed between the data and the geomagnetic field predictions derived from recently reported global models, which reinforces the importance of regional reference curves for dating purposes.
The painted fragments collected during the archaeological excavation campaign in the San Giovanni Battista church in Cevio represent a unique patrimony of Romanesque wall painting in Tessin, Switzerland, having a strong stylistic linkage with the Lombardic art of the same period. The archaeological and stylistic research allowed the fragments to be dated between the 11th and 13th centuries ad and to group them in three chronological phases. The scientific research (p-XRF, OM, SEM–EDS, FTIR and XRD) was aimed at characterizing the pigments and the pictorial techniques used. Important changes occurred in terms of some pigments used during the 11th and 12th centuries: in particular, azurite was used to decorate the earlier wall paintings while lapis lazuli was used for the 12th-century ones. During the second period, lead-based pigments (lead white and minium) were introduced into the palette. The use of natural yellow and red ochres and green earth was common for the three periods. The fresco technique was generally used, except for the application of azurite and lead-based pigments, where the a secco technique was adopted. The integrated research is a contribution to the knowledge of Romanesque art in the Insubric Region.
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