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Organometallics - Aktuelle Forschungsartikel

Aktuelle Forschungsartikel: Metallorganik

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Hier aufgeführte Forschungsartikel:

Organometallics - Herausgeber: American Chemical Society, ACS

'Organometallics' berichtet über Forschungen in einem der aktivsten Bereiche für Metallorganische, Anorganische, Organische Chemiker und Material-Chemiker. Hier wird ausführlich über Synthese, Struktur, Bindung, chemische Reaktivität, Reaktionsmechanismen und Anwendungen von metallorganischen Verbindungen und Organometalloide berichtet. Berichte über Anwendungen umfassen die organische Synthese und die Polymersynthese, katalytische Prozesse und synthetische Aspekte der Materialwissenschaften und der Festkörperchemie.

Wissenschaftliche Fachartikel:

Correction to Structure, Dynamics, and Polymerization Activity of Zirconocenium Ion Pairs Generated with Boron-C6F5 Compounds and Al2R6

Organometallics

DOI: 10.1021/om300090p

Posted on 10 February 2012 | 8:53 pm

Aerobic CO Oxidation of a Metal-Bound Carbonyl in a NHC-Stabilized Cobalt Half-Sandwich Complex

TOC Graphic

Organometallics

DOI: 10.1021/om201037w

Posted on 10 February 2012 | 8:52 pm

Who Wins: Pesci, Peters, or Deacon? Intrinsic Reactivity Orders for Organocuprate Formation via Ligand Decomposition

TOC Graphic

Organometallics

DOI: 10.1021/om2011722

Posted on 10 February 2012 | 3:40 pm

Triphenylamine Derivatives with Para-Disposed Pendant Electron-Rich Organoiron Alkynyl Substituents: Defining the Magnetic Interactions in a Trinuclear Iron(III) Trication

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Organometallics

DOI: 10.1021/om2006358

Posted on 10 February 2012 | 3:40 pm

C–CN Bond Activation of Acetonitrile using Cobalt(I)

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Organometallics

DOI: 10.1021/om201270n

Posted on 9 February 2012 | 10:03 pm

Reactivity of an Oxalamide-Based N-Heterocyclic Carbene

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Organometallics

DOI: 10.1021/om201235c

Posted on 9 February 2012 | 8:23 pm

Synthesis, Air Stability, Photobleaching, and DFT Modeling of Blue Light Emitting Platinum CCC-N-Heterocyclic Carbene Pincer Complexes

TOC Graphic

Organometallics

DOI: 10.1021/om200687w

Posted on 9 February 2012 | 7:46 pm

Reactions of a Triruthenium Pentahydrido Complex with Imines Leading to the Formation of a Perpendicularly Coordinated Iminoacyl Ligand and the Scission of a C?N Bond on a Triruthenium Plane

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Organometallics

DOI: 10.1021/om201230u

Posted on 9 February 2012 | 7:46 pm

Hydrogen Shift Reactions of Rhenium Hydrido Carbyne Complexes

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Organometallics

DOI: 10.1021/om201184m

Posted on 9 February 2012 | 3:48 pm

Regioselective B-Cyclometalation of a Bulky o-Carboranyl Phosphine and the Unexpected Formation of a Dirhodium(II) Complex

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Organometallics

DOI: 10.1021/om201198s

Posted on 9 February 2012 | 3:48 pm

QTAIM View of Metal–Metal Bonding in Di- and Trinuclear Disulfido Carbonyl Clusters

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Organometallics

DOI: 10.1021/om2011744

Posted on 9 February 2012 | 1:42 pm

Formation of a Boraruthenacyclopentenyl Skeleton via B–C Bond Formation across a Triruthenium Plane

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Organometallics

DOI: 10.1021/om201186z

Posted on 9 February 2012 | 1:42 pm

Oxidative Addition Reactions of Bis-Aminophosphine and Bis-Phosphinite Nickel(0) Pincer Complexes

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Organometallics

DOI: 10.1021/om201229x

Posted on 9 February 2012 | 1:42 pm

Reactivity of Boryl Complexes: Synthesis and Structure of New Neutral and Cationic Platinum Boryls and Borylenes

TOC Graphic

Organometallics

DOI: 10.1021/om2012248

Posted on 8 February 2012 | 5:16 pm

On the Mechanism of the [Cp2Mo(OH)(OH2)]+-Catalyzed Nitrile Hydration to Amides: A Theoretical Study

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Organometallics

DOI: 10.1021/om200541z

Posted on 8 February 2012 | 5:15 pm

Resolution and Improved Synthesis of (±)-Arsenicin A: A Natural Adamantane-Type Tetraarsenical Possessing Strong Anti-Acute Promelocytic Leukemia Cell Line Activity

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Organometallics

DOI: 10.1021/om201180d

Posted on 8 February 2012 | 4:22 pm

New Rhodium(I) and Iridium(I) Complexes Containing Mixed Pyrazolyl–1,2,3-Triazolyl Ligands As Catalysts for Hydroamination

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Organometallics

DOI: 10.1021/om201171b

Posted on 8 February 2012 | 2:48 pm

Toward the Ideal Catalyst: From Atomic Centers to a “Cocktail” of Catalysts

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Organometallics

DOI: 10.1021/om201120n

Posted on 8 February 2012 | 2:46 pm

Geminal Carbon–Hydrogen Bond Activation in Cumulenes Promoted by Adjacent Iridium/Ruthenium Centers

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Organometallics

DOI: 10.1021/om201201h

Posted on 8 February 2012 | 2:45 pm

Facile Thermal W–W Bond Homolysis in the N-Heterocyclic Carbene Containing Tungsten Dimer [CpW(CO)2(IMe)]2

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Organometallics

DOI: 10.1021/om201162g

Posted on 8 February 2012 | 2:44 pm

1,3-Dipolar Cycloaddition of Nitrones to a Nitrile Functionality in closo-Decaborate Clusters: A Novel Reactivity Mode for the Borylated C?N Group

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Organometallics

DOI: 10.1021/om200993f

Posted on 7 February 2012 | 8:28 pm

Indenyl Functionalized N-Heterocyclic Carbene Complexes of Chromium: Syntheses, Structures, and Reactivity Studies Relevant to Ethylene Oligomerization and Polymerization

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Organometallics

DOI: 10.1021/om200641u

Posted on 7 February 2012 | 8:27 pm

Reactivity of Lewis Acid Activated Diaza- and Dithiaboroles in Electrophilic Arene Borylation

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Organometallics

DOI: 10.1021/om201228e

Posted on 7 February 2012 | 7:37 pm

Easy Access to Hydride Chemistry on a Tripodal P-Based Rhodium Scaffold

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Organometallics

DOI: 10.1021/om201129j

Posted on 7 February 2012 | 7:24 pm

Synthesis and Characterization of Organolanthanide Complexes with a Calix[4]-pyrrolyl Ligand and Their Catalytic Activities toward Hydrophosphonylation of Aldehydes and Unactivated Ketones

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Organometallics

DOI: 10.1021/om2008925

Posted on 7 February 2012 | 7:23 pm

Theoretical Investigation into the Palladium-Catalyzed Silaboration of Pyridines

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Organometallics

DOI: 10.1021/om2008106

Posted on 7 February 2012 | 7:22 pm

C–H Bond Activation by Cationic Iridium(III) NHC Complexes: A Combined Experimental and Computational Study

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Organometallics

DOI: 10.1021/om2012166

Posted on 7 February 2012 | 2:34 pm

Interaction of the Gold(I) Cation Au(PMe3)+ with Unsaturated Hydrocarbons

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Organometallics

DOI: 10.1021/om2012387

Posted on 6 February 2012 | 2:58 pm

1,1?-Biferrocenylenes?The More Redox Stable Ferrocenes! New Derivatives, Corrected NMR Assignments, Redox Behavior, and Spectroelectrochemistry

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Organometallics

DOI: 10.1021/om201215w

Posted on 6 February 2012 | 2:57 pm

1,3-Double Siloxo-Bridged Zirconium Metallocene for Propene and 1-Hexene Regioselective Oligomerization

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Organometallics

DOI: 10.1021/om2011535

Posted on 6 February 2012 | 2:55 pm

Polymerization Activity Prediction of Zirconocene Single-Site Catalysts Using 3D Quantitative Structure–Activity Relationship Modeling

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Organometallics

DOI: 10.1021/om2007776

Posted on 3 February 2012 | 10:22 pm

The Zwitterion [8,8?-?-CH2O(CH3)-(1,2-C2B9H10)2-3,3?-Co]0 as a Versatile Building Block To Introduce Cobalt Bis(Dicarbollide) Ion into Organic Molecules

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Organometallics

DOI: 10.1021/om200938n

Posted on 3 February 2012 | 4:10 pm

Synthesis and Catalytic Activity in Suzuki Coupling of Nickel Complexes Bearing n-Butyl- and Triethoxysilylpropyl-Substituted NHC Ligands: Toward the Heterogenization of Molecular Catalysts

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Organometallics

DOI: 10.1021/om201101g

Posted on 2 February 2012 | 8:15 pm

Synthesis of Dianionic ?-Diketiminate Lanthanide Amides L?LnN(SiMe3)2(THF) by Deprotonation of the ?-Diketiminate Ligand L (L = {[(2,6-iPr2C6H3)NC(CH3)]2CH}?) and the Transformation with [HNEt3][BPh4] to the Cationic Samarium Amide [LSmN(SiMe3)2][BPh4]

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Organometallics

DOI: 10.1021/om2010904

Posted on 2 February 2012 | 2:52 pm

Trapping of a Doubly Unsaturated Dinuclear Iridium(II) Sulfonylimido Complex with Phosphine and Lewis Acidic Group 11 and 12 Metals

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Organometallics

DOI: 10.1021/om201218j

Posted on 1 February 2012 | 10:43 pm

Versatile 1,2- and 1,3-Dipole Behavior of the 1-Arsa-3-Germaallene Tip(t-Bu)Ge?C?AsMes*: Formation of a Heterocyclic Arsa(germa)carbene (AsGeHC)

TOC Graphic

Organometallics

DOI: 10.1021/om200968x

Posted on 1 February 2012 | 10:42 pm

Influence of the Formation of the Halogen Bond ArX-?-?-N on the Mechanism of Diketonate Ligated Copper-Catalyzed Amination of Aromatic Halides

TOC Graphic

Organometallics

DOI: 10.1021/om200952v

Posted on 1 February 2012 | 10:41 pm

Computational Study on the Palladium-Catalyzed Allenylative Dearomatization Reaction

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Organometallics

DOI: 10.1021/om201248t

Posted on 1 February 2012 | 5:59 pm

Investigation of Iridium CF3PCP Pincer Catalytic Dehydrogenation and Decarbonylation Chemistry

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Organometallics

DOI: 10.1021/om2011886

Posted on 1 February 2012 | 4:53 pm

Rhenium Complexes of 2,3-Di(2-pyridyl)-5,6-diphenylpyrazine: Synthesis, Characterization, and Reactivity

TOC Graphic

Organometallics

DOI: 10.1021/om201240c

Posted on 1 February 2012 | 3:47 pm

Tandem C–F and C–H Bond Activation in Fluoroolefins Promoted by a Bis(diethylphosphino)methane-Bridged Diiridium Complex: Role of Water in the Activation Processes

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Organometallics

DOI: 10.1021/om2011968

Posted on 1 February 2012 | 1:53 pm

(Dimethylamino)borylene and Related Complexes of Electron-Rich Metal Fragments: Generation of Nucleophile-Resistant Cations by Spontaneous Halide Ejection

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Organometallics

DOI: 10.1021/om201144e

Posted on 1 February 2012 | 6:25 am

Electrochemical and Theoretical Studies of the Impact of the Chelating Ligand on the Reactivity of [Fe2(CO)4(?2-LL)(?-pdt)]+ Complexes with Different Substrates (LL = IMe-CH2-IMe, dppe; IMe = 1-Methylimidazol-2-ylidene)

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Organometallics

DOI: 10.1021/om201143p

Posted on 1 February 2012 | 6:24 am

Syntheses and Thermolysis of Arylpalladium Hydroxide Complexes: Implications for C(sp2)–OH Bond-Forming Reductive Elimination To Generate Phenol Derivatives

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Organometallics

DOI: 10.1021/om201142s

Posted on 1 February 2012 | 6:23 am

Tetramethyleneethane as a Bis(allylic) Ligand: 16-Electron Cobalt Configurations in Preference to Cobalt–Cobalt Bonding

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Organometallics

DOI: 10.1021/om201155a

Posted on 31 January 2012 | 5:14 pm

Electronic Coupling in a Bis-Cyclometalated Ruthenium Complex Bridged by 3,3?,5,5?-Tetrakis(1H-1,2,3-triazol-4-yl)biphenyl

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Organometallics

DOI: 10.1021/om201112h

Posted on 31 January 2012 | 5:14 pm

Versatile Synthesis of PR2NR?2 Ligands for Molecular Electrocatalysts with Pendant Bases in the Second Coordination Sphere

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Organometallics

DOI: 10.1021/om201168h

Posted on 31 January 2012 | 6:45 am

Regioselectivity of Insertion and Role of the Anionic Ligands in the Ruthenium Alkylidene Catalyzed Cyclopolymerization of 1,6-Heptadiynes

TOC Graphic

Organometallics

DOI: 10.1021/om2007216

Posted on 30 January 2012 | 10:47 pm

Gold Complexes of an Alicyclic Indazole-Derived N-Heterocyclic Carbene: Syntheses, Characterizations, and Ligand Disproportionation

TOC Graphic

Organometallics

DOI: 10.1021/om201268m

Posted on 30 January 2012 | 7:37 pm

Six-Membered, Chiral NHCs Derived from Camphor: Structure–Reactivity Relationship in Asymmetric Oxindole Synthesis

TOC Graphic

Organometallics

DOI: 10.1021/om201166b

Posted on 30 January 2012 | 7:35 pm

Rhodium(III)-Catalyzed Hydroamination of Aromatic Terminal Alkynes with Anilines

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Organometallics

DOI: 10.1021/om201134j

Posted on 30 January 2012 | 7:33 pm

A Discrete N,O,N-Supported Gallium Amido Complex for the Intermolecular Hydroamination of Terminal Alkynes

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Organometallics

DOI: 10.1021/om2012584

Posted on 30 January 2012 | 5:29 pm

Linear Bis(perfluoroalkyl) Complexes of Nickel Bipyridine

TOC Graphic

Organometallics

DOI: 10.1021/om2012776

Posted on 27 January 2012 | 9:46 pm

Tuning the Regioselectivity of Palladium-Catalyzed Direct Arylation of Azoles by Metal Coordination

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Organometallics

DOI: 10.1021/om2012612

Posted on 27 January 2012 | 9:45 pm

Titanium(IV) Trifluoromethyl Complexes: New Perspectives on Bonding from Organometallic Fluorocarbon Chemistry

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Organometallics

DOI: 10.1021/om201055e

Posted on 27 January 2012 | 2:12 pm

Stoichiometric and Catalytic Reactions of Thermally Stable Nickel(0) NHC Complexes

TOC Graphic

Organometallics

DOI: 10.1021/om300045t

Posted on 27 January 2012 | 6:58 am

Bulk Gold-Catalyzed Reactions of Isocyanides, Amines, and Amine N-Oxides

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Organometallics

DOI: 10.1021/om201068g

Posted on 26 January 2012 | 8:41 pm

MCl2(ampy)(dppf) (M = Ru, Os): Multitasking Catalysts for Carbonyl Compound/Alcohol Interconversion Reactions

TOC Graphic

Organometallics

DOI: 10.1021/om201189r

Posted on 26 January 2012 | 7:02 pm

New Approach to the Synthesis of 3-Alkyl-1,2-dicarba-closo-dodecaboranes: Reaction of Alkyldichloroboranes with Thallium Dicarbollide

TOC Graphic

Organometallics

DOI: 10.1021/om201060e

Posted on 26 January 2012 | 7:01 pm

An Efficient Ferrocene Derivative as a Chromogenic, Optical, and Electrochemical Receptor for Selective Recognition of Mercury(II) in an Aqueous Environment

TOC Graphic

Organometallics

DOI: 10.1021/om201073g

Posted on 26 January 2012 | 1:51 pm

Synthesis of an Arylbromosilylene–Platinum Complex by Using a 1,2-Dibromodisilene As a Silylene Source

TOC Graphic

Organometallics

DOI: 10.1021/om201227p

Posted on 25 January 2012 | 10:32 pm

Effects of Attractive Through Space ?–?* Interactions on the Structure, Reactivity, and Activity of Grubbs II Complexes

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Organometallics

DOI: 10.1021/om201232p

Posted on 25 January 2012 | 7:39 pm

Triazoles from N-Alkynylheterocycles and Their Coordination to Iridium

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Organometallics

DOI: 10.1021/om201157g

Posted on 25 January 2012 | 7:38 pm

C–H Bond Activation of Methane by PtII–N-Heterocyclic Carbene Complexes. The Importance of Having the Ligands in the Right Place at the Right Time

TOC Graphic

Organometallics

DOI: 10.1021/om201114d

Posted on 25 January 2012 | 3:46 pm

Self-Assembly of Heterometallic Metallomacrocycles via Ditopic Fluoroaryl Gold(I) Organometallic Metalloligands

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Organometallics

DOI: 10.1021/om201028q

Posted on 25 January 2012 | 3:46 pm

Efficient One-Pot Synthesis of Unsymmetrical Gold(I) N-Heterocyclic Carbene Complexes and Their Use as Catalysts

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Organometallics

DOI: 10.1021/om2008919

Posted on 25 January 2012 | 3:45 pm

Efficient Route to Organometallic Cage Formation via C–H Activation-Directed Muticomponent Assembly Accompanying Aromatic Guest Encapsulation

TOC Graphic

Organometallics

DOI: 10.1021/om201074k

Posted on 24 January 2012 | 5:08 pm

Cationic Gold(I) Complexes of 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene

TOC Graphic

Organometallics

DOI: 10.1021/om201265n

Posted on 24 January 2012 | 2:00 pm

Ag Complexes of NHC Ligands Bearing Polyfluoroalkyl and/or Polyfluoropolyalkoxy Ponytails. Why Are Polyethers More Fluorous Than Alkyls?

TOC Graphic

Organometallics

DOI: 10.1021/om201062c

Posted on 24 January 2012 | 1:59 pm

Experimental and Theoretical Study of the Living Polymerization of N-Silylphosphoranimines. Synthesis of New Block Copolyphosphazenes

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Organometallics

DOI: 10.1021/om201012g

Posted on 24 January 2012 | 1:59 pm

O–CN Bond Cleavage of Cyanates by a Transition-Metal Complex

TOC Graphic

Organometallics

DOI: 10.1021/om201257h

Posted on 24 January 2012 | 6:58 am

Revisiting the Phospha-Wittig–Horner Reaction

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Organometallics

DOI: 10.1021/om201158k

Posted on 24 January 2012 | 6:19 am

1,3-Diphosphorus Ylide Cyclopentadienylium Salts: Synthesis, Structures, and Application in Coupling Reactions

TOC Graphic

Organometallics

DOI: 10.1021/om201267q

Posted on 23 January 2012 | 9:21 pm

Reactivity of the Phosphinidene-Bridged Complexes [Mo2Cp(?-?1:?1,?5-PC5H4)(?6-1,3,5-C6H3tBu3)(CO)2] and [Mo2Cp2(?-PH)(?6-1,3,5-C6H3tBu3)(CO)2] toward Alkynes: Multicomponent Reactions in the Presence of Ligands

TOC Graphic

Organometallics

DOI: 10.1021/om201048s

Posted on 23 January 2012 | 9:20 pm

A Cationic NCN Pincer Platinum(II) Aquo Complex with a Bis(imidazolinyl)phenyl Ligand: Studies toward its Synthesis and Asymmetric Friedel–Crafts Alkylation of Indoles with Nitroalkenes

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Organometallics

DOI: 10.1021/om200714z

Posted on 23 January 2012 | 1:44 pm

Vinyl Polymerization of Norbornene on Nickel Complexes with Bis(imino)pyridine Ligands Containing Electron-Withdrawing Groups

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Organometallics

DOI: 10.1021/om201213v

Posted on 23 January 2012 | 1:23 pm

Synthesis and Structural Characterization of Nickel(II) Complexes with Imino-N-heterocyclic Carbene Heteroditopic Ligands

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Organometallics

DOI: 10.1021/om2011485

Posted on 23 January 2012 | 1:22 pm

“Click” Chemistry-Mediated Phenylene-Cored Carborane Dendrimers

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Organometallics

DOI: 10.1021/om201255b

Posted on 20 January 2012 | 10:24 pm

Anilidopyridyl-Pyrrolide and Anilidopyridyl-Indolide Group 3 Metal Complexes: Highly Active Initiators for the Ring-Opening Polymerization of rac-Lactide

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Organometallics

DOI: 10.1021/om201251g

Posted on 20 January 2012 | 9:18 pm

Factors Influencing the Outcomes of Intermolecular C–H Activations of Hydrocarbons Initiated by CpW(NO)(CH2CMe3)(?3-allyl) Complexes (Cp = ?5-C5Me5 (Cp*), ?5-C5Me4H (Cp?))

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Organometallics

DOI: 10.1021/om201133r

Posted on 20 January 2012 | 8:51 pm

Experimental Study of the Reaction of a Ni(PEt3)2 Synthon with Polyfluorinated Pyridines: Concerted, Phosphine-Assisted, or Radical C–F Bond Activation Mechanisms?

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Organometallics

DOI: 10.1021/om200990g

Posted on 20 January 2012 | 8:48 pm

Selectivity in the C–H Activation Reaction of CH3OSO2CH3 with [1,2,4-(Me3C)3C5H2]2CeH or [1,2,4-(Me3C)3C5H2][1,2-(Me3C)2-4-(Me2CCH2)C5H2]Ce: To Choose or Not To Choose

TOC Graphic

Organometallics

DOI: 10.1021/om200842t

Posted on 20 January 2012 | 8:36 pm

Platinum-Catalyzed Substitution of Allylic Fluorides

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Organometallics

DOI: 10.1021/om201029m

Posted on 20 January 2012 | 4:39 pm

Ligand Steric and Electronic Effects on ?-Ketiminato Neutral Nickel(II) Olefin Polymerization Catalysts

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Organometallics

DOI: 10.1021/om2010194

Posted on 20 January 2012 | 4:39 pm

[(PhBP3)Cu(PPh3)] as a Surrogate of TpxCuL in Homogeneous Catalysis (PhBP3 = PhB(CH2PPh2)3; Tpx = Hydrotrispyrazolylborate)

TOC Graphic

Organometallics

DOI: 10.1021/om201016b

Posted on 20 January 2012 | 4:38 pm

(Cycloheptadienyl)diphenylphosphine: A Versatile Hybrid Ligand

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Organometallics

DOI: 10.1021/om200999n

Posted on 20 January 2012 | 4:37 pm

Modular Phosphole-Methano-Bridged-Phosphine(Borane) Ligands. Application to Rhodium-Catalyzed Reactions

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Organometallics

DOI: 10.1021/om2008265

Posted on 20 January 2012 | 4:36 pm

Dioxaneferrocenylimine Cyclometalated Compounds as Precursors to Novel Functionalized Di- and Tetranuclear Metallacycles Leading to 1,3-Double Palladation of an ?5-C5H5 Ring

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Organometallics

DOI: 10.1021/om2008698

Posted on 20 January 2012 | 2:01 pm

Bis-Cyclometalation of Fluorinated N-Aryl NHCs

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Organometallics

DOI: 10.1021/om2009809

Posted on 19 January 2012 | 10:57 pm

Stoichiometric Reactivity Relevant to the Mor-DalPhos/Pd-Catalyzed Cross-Coupling of Ammonia and 1-Bromo-2-(phenylethynyl)benzene

TOC Graphic

Organometallics

DOI: 10.1021/om201122q

Posted on 19 January 2012 | 8:46 pm

Nickel and Palladium Complexes with New Phosphinito-Imine Ligands and Their Application as Ethylene Oligomerization Catalysts

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Organometallics

DOI: 10.1021/om201088y

Posted on 19 January 2012 | 7:01 pm

Low-Coordinate Cobalt Fluoride Complexes: Synthesis, Reactions, and Production from C–F Activation Reactions

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Organometallics

DOI: 10.1021/om200991k

Posted on 19 January 2012 | 7:00 pm

Platinum(II) Complexes with Coordinated Electron-Withdrawing Fluoroalkyl and Fluoroaryl Ligands: Synthesis, Reactivity, and Catalytic Activity

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Organometallics

DOI: 10.1021/om200953z

Posted on 19 January 2012 | 7:00 pm

Palladium(II)-Catalyzed Rearrangement and Oligomerization Reactions of cis-Bicyclo[4.2.0]oct-7-ene

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Organometallics

DOI: 10.1021/om200877p

Posted on 19 January 2012 | 7:00 pm

Bulky-Alkyl-Substituted Bis(trifluorovinyl)ferrocenes: Redox-Autocatalytic Formation of Fluorinated Ferrocenophanes

TOC Graphic

Organometallics

DOI: 10.1021/om2009765

Posted on 19 January 2012 | 1:44 pm

4-Tetrafluoropyridyl Silver(I), AgC5F4N, in Redox Transmetalations with Selenium and Tellurium

TOC Graphic

Organometallics

DOI: 10.1021/om201195j

Posted on 18 January 2012 | 10:59 pm

Structurally Similar, Thermally Stable Copper(I), Silver(I), and Gold(I) Ethylene Complexes Supported by a Fluorinated Scorpionate

TOC Graphic

Organometallics

DOI: 10.1021/om201185v

Posted on 18 January 2012 | 9:24 pm

Hydroamination of Unactivated Alkenes Catalyzed by Novel Platinum(II) N-Heterocyclic Carbene Complexes

TOC Graphic

Organometallics

DOI: 10.1021/om200964u

Posted on 18 January 2012 | 7:53 pm

Synthesis and Characterization of the Double Salts [Pt(bzq)(CNR)2][Pt(bzq)(CN)2] with Significant Pt···Pt and ?···? Interactions. Mechanistic Insights into the Ligand Exchange Process from Joint Experimental and DFT Study

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Organometallics

DOI: 10.1021/om201036z

Posted on 18 January 2012 | 5:02 pm

From Anionic N-Heterocyclic Dicarbenes to Abnormal Carbene–Borane Complexes: A Logical Synthetic Route

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Organometallics

DOI: 10.1021/om201259d

Posted on 18 January 2012 | 3:41 pm

Synthesis of Calcium and Ytterbium Complexes Supported by a Tridentate Imino-Amidinate Ligand and Their Application in the Intermolecular Hydrophosphination of Alkenes and Alkynes

TOC Graphic

Organometallics

DOI: 10.1021/om201223j

Posted on 18 January 2012 | 3:39 pm

Thermal Rearrangement via P–C Bond Cleavage of a Tridentate Diphosphine–N-Heterocyclic Carbene Ligand System Coordinated to Rhodium

TOC Graphic

Organometallics

DOI: 10.1021/om201233e

Posted on 18 January 2012 | 1:27 pm

A Cis-Bis-Mixed-Carbene Ruthenium Hydride Complex: An Olefin-Selective Hydrogenation Catalyst

TOC Graphic

Organometallics

DOI: 10.1021/om300014r

Posted on 18 January 2012 | 1:27 pm

Decisive Steps of the Hydrodefluorination of Fluoroaromatics using [Ni(NHC)2]

TOC Graphic

Organometallics

DOI: 10.1021/om2009815

Posted on 18 January 2012 | 6:17 am

Synthesis, Characterization, and Infrared Reflectance Spectroelectrochemistry of Organoruthenium Nitrosyl Porphyrins

TOC Graphic

Organometallics

DOI: 10.1021/om200601g

Posted on 17 January 2012 | 10:43 pm

Bis(acetylacetonate) Tungsten(IV) Complexes Containing a ?-Basic Diazoalkane or Oxo Ligand

TOC Graphic

Organometallics

DOI: 10.1021/om201050j

Posted on 17 January 2012 | 3:14 pm

Synthesis and Reactivity of Nickel and Palladium Fluoride Complexes with PCP Pincer Ligands. NMR-Based Assessment of Electron-Donating Properties of Fluoride and Other Monoanionic Ligands

TOC Graphic

Organometallics

DOI: 10.1021/om2009793

Posted on 17 January 2012 | 3:13 pm

Halostibines SbMeX2 and SbMe2X: Lewis Acids or Lewis Bases?

TOC Graphic

Organometallics

DOI: 10.1021/om2010996

Posted on 13 January 2012 | 3:28 pm

Natural Bond Orbital Analysis of the Electronic Structure of [LnM(CH3)] and [LnM(CF3)] Complexes

TOC Graphic

Organometallics

DOI: 10.1021/om2011003

Posted on 13 January 2012 | 3:01 pm

Asymmetric Synthesis and Metal Complexes of a C3-Symmetric P-Stereogenic Triphosphine, (R)-MeSi(CH2PMe(t-Bu))3 (MT-Siliphos)

TOC Graphic

Organometallics

DOI: 10.1021/om200930k

Posted on 13 January 2012 | 3:00 pm

An Approach to Pin Down the Solid-State Structure of the “Turbo Grignard”

TOC Graphic

Organometallics

DOI: 10.1021/om201080t

Posted on 13 January 2012 | 6:01 am

Palladium Carbene Complexes for Selective Alkene Di- and Oligomerization

TOC Graphic

Organometallics

DOI: 10.1021/om201027y

Posted on 13 January 2012 | 6:01 am

Solid-State Structures of Base-Free Lithium and Sodium Tetraphenylborates at Room and Low Temperature: Comparison with the Higher Homologues MB(C6H5)4 (M = K, Rb, Cs)

TOC Graphic

Organometallics

DOI: 10.1021/om200943n

Posted on 12 January 2012 | 10:17 pm

Reaction of [Ru3(CO)12] with Phenazine: Synthesis of C-Metalated Derivatives That Formally Arise from a C–H Oxidative Addition or a Long-Distance C-to-N Prototropy

TOC Graphic

Organometallics

DOI: 10.1021/om200983a

Posted on 12 January 2012 | 3:52 pm

Heterodinuclear Bridging Carbido and Phosphoniocarbyne Complexes

TOC Graphic

Organometallics

DOI: 10.1021/om201057c

Posted on 11 January 2012 | 2:31 pm

Reactivity of Scandium ?-Diketiminate Alkyl Complexes with Carbon Dioxide

TOC Graphic

Organometallics

DOI: 10.1021/om2012002

Posted on 11 January 2012 | 6:14 am

Dual Reactivity of a Stable Zwitterionic N-Heterocyclic Silylene and Its Carbene Complex Probed with Muonium

TOC Graphic

Organometallics

DOI: 10.1021/om200966p

Posted on 11 January 2012 | 6:14 am

Synthesis and Self-Association of Organoplatinum(IV) Boronic Acids

TOC Graphic

Organometallics

DOI: 10.1021/om2009217

Posted on 10 January 2012 | 10:17 pm

Decamethylferrocene Redox Chemistry and Gold Nanowire Electrodeposition at Salt Crystal|Electrode|Nonpolar Organic Solvent Contacts

TOC Graphic

Organometallics

DOI: 10.1021/om2006112

Posted on 10 January 2012 | 10:16 pm

Pentafluoropropenyl Complexes of Mercury, Germanium, Tin, and Lead Derived from (Z)-CFH?CFCF3 and Their Use as Transfer Reagents

TOC Graphic

Organometallics

DOI: 10.1021/om2009843

Posted on 10 January 2012 | 6:35 am

An Update on Recent Stoichiometric and Catalytic C–F Bond Cleavage Reactions by Lanthanide and Group 4 Transition-Metal Complexes

TOC Graphic

Organometallics

DOI: 10.1021/om200978a

Posted on 9 January 2012 | 9:06 pm

An Easy Conversion from Platinum(II) Reagents to Platinum(IV) Products: ?3 to ?2 Coordination Mode Interconversion, Phenyl Migration, and Ortho C–H Activation Cascade in a Hemilabile “Click”-Triazole Scorpionate Platinum System

TOC Graphic

Organometallics

DOI: 10.1021/om2010595

Posted on 9 January 2012 | 2:48 pm

Co2(CO)6(?,?2-HCCFc) as Precursor in the Synthesis of Multiredox Cyclic and Linear Vinylferrocenylsiloxanes

TOC Graphic

Organometallics

DOI: 10.1021/om201018h

Posted on 6 January 2012 | 3:56 pm

Rhodium Cyclopentyl Phosphine Complexes of Wide-Bite-Angle Ligands DPEphos and Xantphos

TOC Graphic

Organometallics

DOI: 10.1021/om201034m

Posted on 6 January 2012 | 1:56 pm

Exploration of the Mechanism of Platinum(II)-Catalyzed C–F Activation: Characterization and Reactivity of Platinum(IV) Fluoroaryl Complexes Relevant to Catalysis

TOC Graphic

Organometallics

DOI: 10.1021/om2007562

Posted on 5 January 2012 | 4:25 pm

Reactions of Modified Intermolecular Frustrated P/B Lewis Pairs with Dihydrogen, Ethene, and Carbon Dioxide

TOC Graphic

Organometallics

DOI: 10.1021/om201076f

Posted on 4 January 2012 | 8:43 pm

Synthesis and Reactivity of the Fluoro Complex trans-[Pd(F)(4-C5NF4)(iPr2PCH2CH2OCH3)2]: C–F Bond Formation and Catalytic C–F Bond Activation Reactions

TOC Graphic

Organometallics

DOI: 10.1021/om200998d

Posted on 4 January 2012 | 7:36 pm

Palladium-Assisted Room-Temperature Nucleophilic Substitution of an Unactivated Aryl Fluoride

TOC Graphic

Organometallics

DOI: 10.1021/om201175d

Posted on 30 December 2011 | 5:59 pm

CF3–Ph Reductive Elimination from [(Xantphos)Pd(CF3)(Ph)]

TOC Graphic

Organometallics

DOI: 10.1021/om200985g

Posted on 28 December 2011 | 7:52 pm

Efficient and Systematic Click-Based Synthetic Routes to Amino Acid Functionalized Metallatricarbadecaboranes

TOC Graphic

Organometallics

DOI: 10.1021/om201044r

Posted on 23 December 2011 | 7:41 pm

Carbene Complexes of Phosphorus(V) Fluorides by Oxidative Addition of 2,2-Difluorobis(dialkylamines) to Phosphorus(III) Halides

TOC Graphic

Organometallics

DOI: 10.1021/om2009827

Posted on 22 December 2011 | 2:20 pm

Syntheses and Structures of the Crystalline, Highly Crowded 1,3-Bis(trimethylsilyl)cyclopentadienyls [MCp?3] (M = Y, Er, Yb), [PbCp?2], [{YCp?2(?-OH)}2], [(ScCp?2)2(?-?2:?2-C2H4)], [YbCp?2Cl(?-Cl)K(18-crown-6)], and [{KCp?}?]

TOC Graphic

Organometallics

DOI: 10.1021/om2009364

Posted on 21 December 2011 | 3:30 pm

Preparation, Structure, and Reactions of Trifluoroacetimidoyl Palladium(II) Complexes

TOC Graphic

Organometallics

DOI: 10.1021/om201021b

Posted on 21 December 2011 | 2:17 pm

Palladium-Catalyzed Aerobic Dehydrogenative Cross-Coupling of Polyfluoroarenes with Thiophenes: Facile Access to Polyfluoroarene–Thiophene Structure

TOC Graphic

Organometallics

DOI: 10.1021/om200873j

Posted on 19 December 2011 | 7:50 pm

Mercury(II) Complexes of the Carba-closo-dodecaboranyl Ligands [closo-1-CB11X11]2– (X = H, F, Cl, Br, I)

TOC Graphic

Organometallics

DOI: 10.1021/om201023h

Posted on 16 December 2011 | 2:25 pm

Benzylidyne Bridges from Diphenylacetylene and a Methylidyne Bridge from Methylmagnesium Chloride

TOC Graphic

Organometallics

DOI: 10.1021/om200383x

Posted on 15 December 2011 | 6:13 am

Aluminum Complexes of Bidentate Fluorinated Alkoxy-Imino Ligands: Syntheses, Structures, and Use in Ring-Opening Polymerization of Cyclic Esters

TOC Graphic

Organometallics

DOI: 10.1021/om200907x

Posted on 8 December 2011 | 10:03 pm

Indium Complexes of Fluorinated Dialkoxy-Diimino Salen-like Ligands for Ring-Opening Polymerization of rac-Lactide: How Does Indium Compare to Aluminum?

TOC Graphic

Organometallics

DOI: 10.1021/om200906e

Posted on 6 December 2011 | 10:18 pm

Reactivity of “Ligand-Free” Au+: C–H and C–C Activation versus ? Coordination

TOC Graphic

Organometallics

DOI: 10.1021/om201035v

Posted on 2 December 2011 | 4:41 pm

Pentafluorophenyl Copper–Pyridine Complexes: Synthesis, Supramolecular Structures via Cuprophilic and ?-Stacking Interactions, and Solid-State Luminescence

TOC Graphic

Organometallics

DOI: 10.1021/om200989b

Posted on 1 December 2011 | 7:32 pm

Reaction of Terminal Phosphinidene Complexes with Dihydrogen

TOC Graphic

Organometallics

DOI: 10.1021/om2009974

Posted on 30 November 2011 | 4:03 pm

Synthesis and Reactivity of [PdCl2{C,N-C6H4C(?NHXy)NH2-2}] and Neutral Palladium 1,2-Dihydroquinazolinium-4-yl Complexes: Depalladation Reactions

TOC Graphic

Organometallics

DOI: 10.1021/om200986k

Posted on 29 November 2011 | 10:07 pm

Polyhedral Platinaborane Chemistry. Interaction of PMe2Ph with [(PMe2Ph)2PtB10H12]

TOC Graphic

Organometallics

DOI: 10.1021/om200940h

Posted on 29 November 2011 | 9:16 pm

Breaking C–F Bonds via Nucleophilic Attack of Coordinated Ligands: Transformations from C–F to C–X Bonds (X= H, N, O, S)

TOC Graphic

Organometallics

DOI: 10.1021/om2010386

Posted on 29 November 2011 | 5:18 pm

Reactions of Half-Sandwich Ethene Complexes of Rhodium(I) toward Iodoperfluorocarbons: Perfluoro-alkylation or -arylation of Coordinated Ethene versus Oxidative Addition

TOC Graphic

Organometallics

DOI: 10.1021/om2009588

Posted on 29 November 2011 | 5:17 pm

Gold Chemistry Guided by the Isolobality Concept†

TOC Graphic

Organometallics

DOI: 10.1021/om2010113

Posted on 23 November 2011 | 4:32 pm

Reactions of Osmium–Pinacolboryl Complexes: Preparation of the First Vinylideneboronate Esters

TOC Graphic

Organometallics

DOI: 10.1021/om200485k

Posted on 22 November 2011 | 8:24 pm

Hydrofluoroarylation of Alkynes with Ni Catalysts. C–H Activation via Ligand-to-Ligand Hydrogen Transfer, an Alternative to Oxidative Addition

TOC Graphic

Organometallics

DOI: 10.1021/om2005673

Posted on 22 November 2011 | 3:10 pm

Ferrocenes Containing a Pendant Propargylic Chain Obtained via Addition of Propargyl Alcohol to ?-Vinyliminium Ligands in Diiron Complexes

TOC Graphic

Organometallics

DOI: 10.1021/om200904s

Posted on 22 November 2011 | 2:04 pm

Phosphine Complexes of an Enantiomerically Pure, Atropisomeric Arsenium Ion

TOC Graphic

Organometallics

DOI: 10.1021/om200853d

Posted on 21 November 2011 | 6:32 am

Palladium-Catalyzed Cross-Coupling Reactions with Fluorinated Substrates: Mechanistic Insights into the Undesired Hydrodehalogenation of Aryl Halides

TOC Graphic

Organometallics

DOI: 10.1021/om200898t

Posted on 2 November 2011 | 4:59 pm

Substitution of Tetracyanoethene by Ethynyl–Metal Complexes Gives Tricyanovinylethynyl (Tricyanobutenynyl) Derivatives: Syntheses, Protonation, and Addition of Metal–Ligand Fragments

TOC Graphic

Organometallics

DOI: 10.1021/om2007503

Posted on 1 November 2011 | 5:47 pm

Trimethylsilyl-Substituted Hydroxycyclopentadienyl Ruthenium Hydrides as Benchmarks To Probe Ligand and Metal Effects on the Reactivity of Shvo Type Complexes

TOC Graphic

Organometallics

DOI: 10.1021/om2007453

Posted on 21 October 2011 | 9:25 pm

Fluorine in Cyclometalated Platinum Compounds

TOC Graphic

Organometallics

DOI: 10.1021/om200835g

Posted on 20 October 2011 | 10:57 pm

Air-Stable and Catalytically Active Phosphinous Acid Transition-Metal Complexes

TOC Graphic

Organometallics

DOI: 10.1021/om200697u

Posted on 14 October 2011 | 3:34 pm

Brønsted Acid/Base Driven Chemistry with Rhodathiaboranes: A Labile {SB9H9}–Thiadecaborane Fragment System

TOC Graphic

Organometallics

DOI: 10.1021/om200707m

Posted on 8 October 2011 | 6:21 am

Facile Isomerization and Unprecedented Decarbonation of Metallacarboranes with Fluorinated Aryl Substituents

TOC Graphic

Organometallics

DOI: 10.1021/om200691z

Posted on 19 September 2011 | 2:52 pm

?-Cleavage of Phenyl Groups from GePh3 Ligands in Iridium Carbonyl Cluster Complexes. A Mechanism and Its Role in the Synthesis of Bridging Germylene Ligands

TOC Graphic

Organometallics

DOI: 10.1021/om2007002

Posted on 15 September 2011 | 2:52 pm

Controlled Hydrosilylation of Carbonyls and Imines Catalyzed by a Cationic Aluminum Alkyl Complex

TOC Graphic

Organometallics

DOI: 10.1021/om2008277

Posted on 14 September 2011 | 8:24 pm

Iron-Catalyzed Cross-Coupling Reactions between Arylzinc Reagents and Alkyl Halides Bearing ?-Fluorines

TOC Graphic

Organometallics

DOI: 10.1021/om2005904

Posted on 7 September 2011 | 7:50 am

An Efficient and Recyclable Catalytic System Comprising Nano-Iridium(0) and a Pyridinium Salt of nido-Carboranyldiphosphine for the Synthesis of One-Dimensional Boronate Esters via Hydroboration Reaction

TOC Graphic

Organometallics

DOI: 10.1021/om200379c

Posted on 17 August 2011 | 9:13 pm

N-Heterocyclic Dicarbene Iridium(III) Pincer Complexes Featuring Mixed NHC/Abnormal NHC Ligands and Their Applications in the Transfer Dehydrogenation of Cyclooctane

TOC Graphic

Organometallics

DOI: 10.1021/om200444q

Posted on 29 July 2011 | 5:59 pm

Luminescent Homo- and Heteropolynuclear Gold Complexes Stabilized by a Unique Acetylide Fragment

TOC Graphic

Organometallics

DOI: 10.1021/om200397t

Posted on 5 July 2011 | 8:06 pm

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