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Green Chemistry - Aktuelle Forschungsartikel



Aktuelle Forschungsartikel: Nachhaltige Chemie

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Green Chemistry - Herausgeber: Royal Society of Chemistry, RSC

Die Zeitschrift veröffentlicht Forschungsarbeiten, die versuchen, die Umweltauswirkungen der chemischen Prozesse durch die Entwicklung einer technologischen Basis, die für die Natur unbedenklich ist, zu verringern.




Wissenschaftliche Fachartikel:



Patterned growth of nanocrystalline silicon thin films through magnesiothermic reduction of soda lime glass

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16459K, Communication
Deniz P. Wong, Hsiang-Ting Lien, Yit-Tsong Chen, Kuei-Hsien Chen, Li-Chyong Chen
In this study, we report a novel, low-cost and green process in synthesizing nc-Si thin films with the possibility of mass production and pattern formation.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Posted on 10 February 2012 | 1:00 am


An atom-efficient synthetic method: carbosilylations of alkenes, alkynes, and cyclic acetals using Lewis and Bronsted acid catalysts

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16291A, Critical Review
Ken Motokura, Toshihide Baba
Catalytic allylsilylations and arylsilylations of alkenes, alkynes, and cyclic acetals using homogeneous and heterogeneous Lewis and Bronsted acids are summarized.
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Posted on 10 February 2012 | 1:00 am


Synthesis of novel fused heterocycle-oxa-aza-phenanthrene and anthracene derivatives via sequential one-pot synthesis in aqueous micellar system

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16425F, Communication
Madhulika Srivastava, Jaya Singh, Shyam B. Singh, Kamleshwar Tiwari, Vijay K. Pathak, Jagdamba Singh
Oxa-aza-phenanthrene and anthracene derivatives which contain a bridgehead nitrogen are synthesized in an aqueous micellar system. The synthetic route is easy and yield is excellent. In this proposed method, solvent, base and surfactant are optimized and the best result was obtained by DBU in water with surfactant CTAB. This method is an efficient, viable and sequential one pot synthetic route for the construction of desired product.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Posted on 10 February 2012 | 1:00 am


Nano rod-shaped and reusable basic Al2O3 catalyst for N-formylation of amines under solvent-free conditions: A novel, practical and convenient 'NOSE' approach

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16020J, Paper
Vijay Kumar Das, Rashmi Rekha Devi, Prasanta Kumar Raul, Ashim Jyoti Thakur
An efficient 'NOSE' protocol for the N-formylation of amines catalyzed by rod-shaped basic nano Al2O3 has been developed.
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Posted on 10 February 2012 | 1:00 am


Microwave-assisted synthesis of 2,3-dihydropyrido[2,3-d]pyrimidin-4(1H)-ones catalyzed by DBU in aqueous medium

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16469H, Paper
Liupan Yang, Daxin Shi, Shu Chen, Hongxin Chai, Danfei Huang, Qi Zhang, Jiarong Li
An efficient and green protocol for synthesis of 2,3-dihydropyrido[2,3-d]pyrimidin-4(1H)-ones catalyzed by DBU under microwave irradiation in water has been developed.
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Posted on 10 February 2012 | 1:00 am


Thiamine hydrochloride (VB1): an efficient promoter for the one-pot synthesis of benzo[4,5]imidazo[1,2-a]pyrimidine and [1,2,4]triazolo[1,5-a]pyrimidine derivatives in water medium

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16499J, Paper
Junhua Liu, Min Lei, Lihong Hu
An efficient and rapid procedure for the synthesis of benzo[4,5]imidazo[1,2-a]pyrimidine and [1,2,4]triazolo[1,5-a]pyrimidine derivatives catalyzed by thiamine hydrochloride (VB1) in water has been developed.
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Posted on 10 February 2012 | 1:00 am


New aspects for biomass processing with ionic liquids: towards the isolation of pharmaceutically active betulin

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16389F, Paper
Anna K. Ressmann, Katharina Strassl, Peter Gaertner, Bin Zhao, Lasse Greiner, Katharina Bica
By utilising ionic liquids the pharmaceutically active triterpene betulin can be extracted from biomass with significantly improved extraction yield and purity.
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Posted on 10 February 2012 | 1:00 am


Natural polyphenols as safe alternatives to hydroquinone for the organocatalyzed reduction of dioxygen dissolved in water by diethylhydroxylamine (DEHA)

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16503A, Paper
Raphael Lebeuf, Ying Zhu, Veronique Nardello-Rataj, Jean-Pierre Lallier, Jean-Marie Aubry
Natural polyphenols as safe alternatives to hydroquinone for the organocatalyzed reduction of dioxygen dissolved in water by diethylhydroxylamine (DEHA).
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Posted on 9 February 2012 | 1:00 am


Design, synthesis, and solution behaviour of small polyamines as switchable water additives

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16240G, Paper
Sean M. Mercer, Tobias Robert, Daniel V. Dixon, Chien-Shun Chen, Zahra Ghoshouni, Jitendra R. Harjani, Soran Jahangiri, Gilles H. Peslherbe, Philip G. Jessop
Switchable water, an aqueous solvent with switchable ionic strength, requires CO2 (as the trigger) and a polyamine ionogen, for which structural design principles are described.
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Posted on 9 February 2012 | 1:00 am


Fast, solvent-free and hydrogen-bonding-mediated asymmetric Michael addition in a ball mill

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16521J, Communication
Yi-Feng Wang, Ru-Xiang Chen, Ke Wang, Bin-Bin Zhang, Zhao-Bo Li, Dan-Qian Xu
We report a highly efficient H-bonding-mediated enantioselective Michael addition reaction in a planetary ball mill.
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Posted on 9 February 2012 | 1:00 am


Power dissipation in microwave-enhanced in situ transesterification of algal biomass to biodiesel

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16195H, Paper
Prafulla D. Patil, Harvind Reddy, Tapaswy Muppaneni, Aravind Mannarswamy, Tanner Schuab, F. Omar Holguin, Peter Lammers, Nagamany Nirmalakhandan, Peter Cooke, Shuguang Deng
We investigated the effect of power dissipation on microwave-accelerated simultaneous extraction and transesterification of dry algal biomass (Nannochloropsis salina) to biodiesel.
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Posted on 8 February 2012 | 1:00 am


Halogen-free ultra-high flame retardant polymers through enzyme catalysis

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16192C, Paper
Sethumadhavan Ravichandran, Subhalakshmi Nagarajan, Bon Choel Ku, Bryan Coughlin, Todd Emrick, Jayant Kumar, Ramaswamy Nagarajan
Biocatalytic green polymerization of substituted deoxybenzoins in predominantly aqueous conditions for the synthesis of ultra-high flame retardant poly(deoxybenzoins) with high char forming capability and low heat release capacities.
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Posted on 8 February 2012 | 1:00 am


Template-free synthesis of an electroactive Au-Calix-PPY nanocomposite for electrochemical sensor applications

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16232F, Paper
Shivani Tanwar, Min-Chieh Chuang, K. Sudhakara Prasad, Ja-an Annie Ho
An eco-friendly approach to synthesize the nanocomposite is described, herein. Synthesis parameters were optimized, the material is well characterized, possesses high electrocatalytic activity and applicability as a sensor for formaldehyde and enzyme free glucose detection.
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Posted on 8 February 2012 | 1:00 am


Natural biopolymer surface of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)-photoinduced modification with triarylsulfonium salts

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16399C, Paper
Davy-Louis Versace, Pierre Dubot, Pierre Cenedese, Jacques Lalevee, Olivier Soppera, Jean-Pierre Malval, Estelle Renard, Valerie Langlois
Efficient green UV-photografting method for modifying PHBHV film in aqueous media to develop biological microdevices.
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Posted on 3 February 2012 | 1:00 am


Photooxygenations in a bubble column reactor

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16439F, Communication
Alexander Yavorskyy, Oksana Shvydkiv, Carolin Limburg, Kieran Nolan, Yan M. C. Delaure, Michael Oelgemoller
A novel column reactor was constructed and successfully applied to dye-sensitized photooxygenation reactions in aqueous alcohol solutions.
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Posted on 1 February 2012 | 1:00 am


An aqueous pathway to polymeric foaming with nanoclay

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16313F, Paper
G. Harikrishnan, Sachchida N. Singh, Chris I. Lindsay, Christopher W. Macosko
A green route for synthesis of foamed polymer nanocomposite is introduced. The technique uses an aqueous route which bypasses the organic surface modification of clay. The use of intermediate solubilization agents for clay dispersion is also avoided.
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Posted on 30 January 2012 | 1:00 am


Preparation of clay-supported Sn catalysts and application to Baeyer-Villiger oxidation

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16437J, Paper
Takayoshi Hara, Moriaki Hatakeyama, Arum Kim, Nobuyuki Ichikuni, Shogo Shimazu
Clay-intercalated Sn catalysts show extremely high performance in Bayer-Villiger oxidation and are reusable without any significant loss of activity or selectivity.
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Posted on 30 January 2012 | 1:00 am


Recyclable and stable ruthenium catalyst for free radical polymerization at ambient temperature initiated by visible light photocatalysis

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16409D, Communication
Guan Zhang, In Young Song, Taiho Park, Wonyong Choi
A ruthenium complex catalyst immobilized on Nafion coated silica shows recyclable and stable photocatalytic activity for free radical polymerization at mild conditions.
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Posted on 30 January 2012 | 1:00 am


Transition metal based catalysts in the aerobic oxidation of alcohols

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16344F, Tutorial Review
Camilla Parmeggiani, Francesca Cardona
Environmentally friendly oxidations of alcohols: implementation of a transition metal-based catalyst with oxygen is an emerging alternative to traditional procedures.
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Posted on 30 January 2012 | 1:00 am


The impact of ionic liquid pretreatment on the chemistry and enzymatic digestibility of Pinus radiata compression wood

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16362D, Paper
Kirk M. Torr, Karen T. Love, Ozgul P. Cetinkol, Lloyd A. Donaldson, Anthe George, Bradley M. Holmes, Blake A. Simmons
Pretreatment with 1-ethyl-3-methylimidazolium acetate induced chemical and structural changes in pine compression wood and improved enzymatic cellulose hydrolysis by 25-fold.
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Posted on 30 January 2012 | 1:00 am


Efficient conversion of microcrystalline cellulose to 1,2-alkanediols over supported Ni catalysts

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC15946E, Paper
Xicheng Wang, Lingqian Meng, Feng Wu, Yijun Jiang, Lei Wang, Xindong Mu
High yield of 1,2-alkanediols can be produced via one-pot catalytic hydrogenolysis of high-crystalline cellulose over Ni/ZnO catalysts.
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Posted on 25 January 2012 | 1:00 am


Catalytic conversion of cellulose to hexitols with mesoporous carbon supported Ni-based bimetallic catalysts

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16364K, Communication
Jifeng Pang, Aiqin Wang, Mingyuan Zheng, Yanhua Zhang, Yanqiang Huang, Xiaowei Chen, Tao Zhang
Robust and highly active Ni-based bimetallic catalysts supported on mesoporous carbon have been developed for catalytic conversion of cellulose to hexitols, over which the maximum hexitol yield reached 59.8%.
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Posted on 25 January 2012 | 1:00 am


Direct synthesis of unsymmetrical ethers from alcohols catalyzed by titanium cation-exchanged montmorillonite

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16135D, Communication
Takato Mitsudome, Tsuyoshi Matsuno, Shoichiro Sueoka, Tomoo Mizugaki, Koichiro Jitsukawa, Kiyotomi Kaneda
Titanium-exchanged montmorillonite (Ti4+-mont) was found to act as an efficient heterogeneous catalyst for the etherification of various alcohols under mild reaction conditions. Ti4+-mont was reusable and applicable to scale-up conditions.
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Posted on 25 January 2012 | 1:00 am


Domino reactions in water: diastereoselective synthesis of densely functionalized indolyldihydrofuran derivatives

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16517A, Paper
Pethaiah Gunasekaran, Kamaraj Balamurugan, Sathiyamoorthi Sivakumar, Subbu Perumal, J. Carlos Menendez, Abdulrahman I. Almansour
A library of trans-5-aroyl-2-(indol-3-yl)-4-aryl-4,5-dihydrofuran-3-carbonitriles was diastereoselectively synthesized in excellent yields from the reaction of 2-(3-indolylcarbonyl)-3-aryl-2-propenenitriles with (2-aryl-2-oxoethyl)pyridinium bromides in the presence of triethylamine via a simple, user-friendly domino process carried out in water.
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Posted on 23 January 2012 | 1:00 am


A one-pot hydrothermal synthesis of tunable dual heteroatom-doped carbon microspheres

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16415A, Paper
Stephanie-Angelika Wohlgemuth, Filipe Vilela, Maria-Magdalena Titirici, Markus Antonietti
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Posted on 18 January 2012 | 1:00 am


Production and purification of an extracellular lipolytic enzyme using ionic liquid-based aqueous two-phase systems

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16428K, Paper
Sonia Patricia Marques Ventura, Rafael Lemos Freire de Barros, Jose Murillo de Pinho Barbosa, Cleide Mara Faria Soares, Alvaro Silva Lima, Joao Araujo Pereira Coutinho
The successful use of IL-based ATPS as separation techniques for the extraction and purification of enzymes from a fermentation process
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Posted on 18 January 2012 | 1:00 am


Measuring the effect of ionic liquids on laccase activity using a simple, parallel method

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16009A, Paper
Lars Rehmann, Ekaterina Ivanova, Jamie L. Ferguson, H. Q. Nimal Gunaratne, Kenneth R. Seddon, Gillian M. Stephens
Laccases catalyse lignin depolymerisation and numerous other industrially useful processes. Using a new parallel assay, we show that laccase retains activity in the presence of a number of ionic liquids.
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Posted on 18 January 2012 | 1:00 am


An in-water, on-water domino process for synthesis

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16259H, Communication
Philip Norcott, Calan Spielman, Christopher S. P. McErlean
By exploiting the different aqueous solubility of organic molecules, a domino process involving in-water and on-water chemistry has been developed. Water is utilized as a reaction medium, a product partitioner and a reaction catalyst.
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Posted on 18 January 2012 | 1:00 am


Transamidation of amides with amines under solvent-free conditions using a CeO2 catalyst

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16316K, Paper
Masazumi Tamura, Takuya Tonomura, Ken-ichi Shimizu, Atsushi Satsuma
Commercial ceria effectively catalyzes transamidation of various primary amides with various amines to yield corresponding N-alkyl amides under solvent-free conditions.
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Posted on 17 January 2012 | 1:00 am


A highly active magnetically recoverable nano ferrite-glutathione-copper (nano-FGT-Cu) catalyst for Huisgen 1,3-dipolar cycloadditions

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16301B, Paper
R. B. Nasir Baig, Rajender S. Varma
Magnetically recoverable heterogeneous Cu catalyst has been used for an eco-friendly synthesis of 1,2,3-triazoles via one-pot multi component reaction using MW irradiation. The catalyst was easily recovered using external magnet and reused in subsequent reactions.
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Posted on 17 January 2012 | 1:00 am


Using water, light, air and spirulina to access a wide variety of polyoxygenated compounds

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16397G, Communication
Dimitris Noutsias, Ioanna Alexopoulou, Tamsyn Montagnon, Georgios Vassilikogiannakis
Air, light, water and spirulina are used to transform readily accessible furan substrates into a diverse range of synthetically useful polyoxygenated motifs
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Posted on 16 January 2012 | 1:00 am


Advances in cellulose chemistry - microwave-assisted synthesis of propargylcellulose in aqueous medium

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16300D, Communication
Pierre-Antoine Faugeras, Pierre-Henri Elchinger, Francois Brouillette, Daniel Montplaisir, Rachida Zerrouki
Propargylation of cellulose has been performed and studied in alkaline aqueous medium leading to DS of 0.35 to 1.88.
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Posted on 16 January 2012 | 1:00 am


Solvent-free and efficient synthesis of imidazo[1,2-a]pyridine derivatives via a one-pot three-component reaction

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16388H, Paper
Li-Rong Wen, Zhao-Rui Li, Ming Li, Han Cao
A synthesis of imidazo[1,2-a]pyridines has been developed by annulation of heterocyclic ketene aminals and [small beta]-oxodithioesters with aldehydes under solvent-free conditions.
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Posted on 13 January 2012 | 1:00 am


Sn-Beta catalysed conversion of hemicellulosic sugars

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16202D, Paper
Martin S. Holm, Yomaira J. Pagan-Torres, Shunmugavel Saravanamurugan, Anders Riisager, James A. Dumesic, Esben Taarning
Pentoses are converted to methyl lactate and related products in yields in the range of 53-55% using Sn-Beta at moderate conditions. The Sn-Beta catalyst shows little discrepancy towards different sugar isomers as it is capable of isomerising them at the reaction conditions. This allows for a simple way to convert a sugar mixture into a relatively well defined product composition that can be purified by distillation.
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Posted on 13 January 2012 | 1:00 am


A sustainable process for the production of [gamma]-valerolactone by hydrogenation of biomass-derived levulinic acid

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC15872H, Paper
Anna Maria Raspolli Galletti, Claudia Antonetti, Valentina De Luise, Marco Martinelli
A sustainable process for the hydrogenation of aqueous levulinic acid (LA) to [gamma]-valerolactone (GVL) has been accomplished under mild reaction conditions exploiting the synergism between heterogeneous ruthenium and acid catalysts.
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Posted on 13 January 2012 | 1:00 am


A practicable environmentally benign one-pot synthesis of 2-arylbenzofurans at room temperature

Green Chem., 2012, Advance Article
DOI: 10.1039/C2GC16181H, Paper
Lian-Yan Liao, Gang Shen, Xue Zhang, Xin-Fang Duan
A simple, practicable and environmentally friendly protocol for the one-pot synthesis of 2-arylbenzofurans under benign conditions has been developed.
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Posted on 13 January 2012 | 1:00 am







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