Komplexchemie und Koordinationschemie - Aktuelle Forschungsartikel
Komplexchemie - Aktuelle Forschungsartikel zum Thema Komplexchemie und Koordinationschemie
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beruecksichtige naturwissenschaftliche Journale:
Journal of Coordination Chemistry - published by
Taylor and Francis -
... publishes the results of original investigations involving the physical and chemical properties, syntheses and structures of coordination compounds.
Russian Journal of Coordination Chemistry - published by
Springer -
... presents reviews, original papers, and communications on all aspects of theoretical and experimental coordination chemistry.
Coordination Chemistry Reviews - published by
Elsevier -
... offers rapid publication of review articles on topics of current interest and importance in coordination chemistry
Aktuelle wissenschaftliche Fachartikel der
genannten Journale:
The topological analysis and systematization of basis lattices in 1972 coordination compounds of Cu, Ag, Cd, and Zn containing
organic ligands and layered complex groups (both isolated and interlaced with each other) are carried out by the TOPOS structural
topological program package. The structures considered are most frequently based on the square (sql) or hexagonal (hcb) Shubnikov lattice (38.6 and 18.7%, respectively). The increased specificity of the sql and hcb lattices is due to specific features of coordination of the lattices facilitating their mutual penetration. Two types of
interlacing of the layered groups (parallel and inclined) are revealed, and the former predominates.
Content Type Journal Article
Pages 309-314
DOI 10.1134/S1070328412040082
Authors
T. G. Mitina, Samara State University, Samara, Russia
D. R. Khamitova, Samara State University, Samara, Russia
V. A. Blatov, Samara State University, Samara, Russia
Treatment in different proportions of 1,2-diaminobenzene with Ni(OAc)2 · 4H2O in methanol results in the formation of two 1,2-diaminobenzene-Ni complexes I (C92H134N24Ni9O28) and II (C16H22N4NiO4). Their structures were determined by X-ray diffraction analysis. The complexes are also characterized by elemental analysis
and IR.
Content Type Journal Article
Pages 337-341
DOI 10.1134/S1070328412050077
Authors
L. Mei, Hefei University of Technology, Hefei, 230009 P.R. China
L. S. Tai, Hefei University of Technology, Hefei, 230009 P.R. China
Z. S. Ming, University of Science and Technology of China, Hefei, 230009 P.R. China
S. Jie, Shanghai Institute of Organic Chemistry, Shanghai, 200032 P.R. China
L. Q. Rong, University of Science and Technology of China, Hefei, 230009 P.R. China
Stereoisomeric Pt(IV) complexes with threonine (ThrH = HOCH(CH3)CH(NH2)COOH, α-amino-β-hydroxybutyric acid) were obtained. In the complexes trans-[Pt(S-ThrH)2Cl4] and trans-[Pt(R-ThrH)(S-ThrH)Cl4], the ThrH molecules act as monodentate ligands coordinated through the NH2 group. In the complexes cis- and trans-[Pt(S-Thr)2Cl2] and trans-[Pt(R-Thr)(S-Thr)Cl2], the deprotonated ligands are coordinated in a bidentate fashion through the NH2 and COO−-groups (R,S is the absolute configuration of the asymmetric carbon atom). All the complexes were identified using elemental analysis,
IR spectroscopy, and 195Pt, 13C, and 1H NMR spectroscopy. The complexes trans-[Pt(S-ThrH)2Cl4] · 3H2O and cis-[Pt(S-Thr)2Cl2] · 2H2O were additionally characterized by X-ray diffraction.
Content Type Journal Article
Pages 363-372
DOI 10.1134/S1070328412040069
Authors
L. F. Krylova, Novosibirsk State University, Novosibirsk, Russia
L. M. Kovtunova, Novosibirsk State University, Novosibirsk, Russia
G. V. Romanenko, Institute “International Tomography Center”, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
L. A. Sheludyakova, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
The reaction of high-molecular weight heparin with Mn2+, Ni2+, Fe3+, and Co2+ in aqueous solution at 37°C with 0.154 M NaCl as the supporting electrolyte was studied by pH-metry and mathematical modeling.
The formation of complex species of different compositions and stabilities was detected. The stability constants of the complexes
were determined.
Content Type Journal Article
Pages 373-378
DOI 10.1134/S1070328412040033
Authors
M. A. Feofanova, Tver State University, Sadovyi per. 35, Tver, Russia
Yu. V. Frantseva, Tver State University, Sadovyi per. 35, Tver, Russia
S. V. Lapshin, Tver State University, Sadovyi per. 35, Tver, Russia
A new Schiff base coordination polymer, [Ni(C18H16N3O2)2 · 2CH3OH]n (C18H16N3O2, 2-acetylpyridine-L-tryptophan), was synthesized and characterized by IR, UV, and X-ray diffraction singlecrystal analysis.
The crystal crystallizes in the tetragonal crystal system, space group P43212 with cell parameters a = 11.8912(11), c = 28.822(3) Å, V = 4075.5(6) Å3, Z = 4, F(000) = 1544, S = 1.187, ρcalcd = 1.199 g cm−3, μ = 0.525 mm−1, the final R1 = 0.0515 and wR2 = 0.1513 for 3602 observed reflections (I > 2σ(I)). The Ni(II) atom is six-coordinated by two nitrogen atoms from C=N, two nitrogen atoms from pyridine rings and two carboxylic
oxygen atoms in different ligands, forming a distorted octahedron geometry. Each ligand serves as a bridging ligand to link
Ni2+ ions through carboxylic oxygen atoms, leading to a two-dimensional coordination polymer.
Content Type Journal Article
Pages 349-352
DOI 10.1134/S1070328412050119
Authors
N. Zhang, Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, 266100 P.R. China
Y. H. Fan, Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, 266100 P.R. China
C. F. Bi, Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, 266100 P.R. China
J. Zuo, Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, 266100 P.R. China
Q. Wang, Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, 266100 P.R. China
The metal exchange reactions of cadmium 5-monoaza-2,3,7,8,12,13,17,18-octamethylporphyrinate with CuCl2 and ZnCl2 in dimethyl sulfoxide (DMSO) were studied by spectrophotometry. The kinetic and energy parameters of the metal exchange reaction
were determined. The possible stoichiometric mechanism of the metal exchange reaction was proposed. A comparative analysis
of the reaction rate constants obtained for the metal exchange and for the complex formation of 5-monoaza-2,3,7,8,12,13,17,18-octamethylporphyrin
with the same salts in DMSO was performed.
Content Type Journal Article
Pages 319-324
DOI 10.1134/S1070328412050120
Authors
S. V. Zvezdina, Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045 Russia
N. Zh. Mamardashvili, Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045 Russia
A novel coordination polymer {[Cd(Pmal)(Bipy)] · 4H2O}n (I), where Bipy = 2,2′-Bipyridine, Pmal = phenethylmalonate, has been synthesized and characterized using IR, 1H NMR, elemental analysis, and single-crystal X-ray diffractometry. The unit cell parameters for complex I: a = 12.3752(15), b = 6.8283(9), c = 13.4739(17) Å, β = 91.108(2)°, V = 1138.4(2) Å3, Z = 2, space group P21. The binding of complex I with fish sperm DNA (FS-DNA) was investigated by fluorescence spectroscopy, showing that the complex has the ability of interaction
with DNA. Gel-electrophoresis assay demonstrates the ability of complex I to cleave the pBR322 plasmid DNA.
Content Type Journal Article
Pages 325-330
DOI 10.1134/S1070328412040045
Authors
E. J. Gao, Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142 P.R. China
B. Wang, Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142 P.R. China
L. Lin, Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142 P.R. China
T. D. Sun, Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142 P.R. China
Z. Wen, Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142 P.R. China
S. H. Liu, Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142 P.R. China
Y. Wang, Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142 P.R. China
R. S. Wang, Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142 P.R. China
Y. Zhang, Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142 P.R. China
M. Zhang, Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142 P.R. China
Y. X. Zhang, Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142 P.R. China
M. C. Zhu, Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142 P.R. China
L. Liu, Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142 P.R. China
New complexes of Co(II), Ni(II), and Cu(II) nitrates, chlorides, and perchlorates with 4-(4-hydroxyphenyl)-1,2,4-triazole
(L) were obtained and examined by single-crystal X-ray diffraction, X-ray powder diffraction, and electronic absorption and
IR spectroscopy. The cations of all the complexes have linear trinuclear structures. Ligand L is coordinated to the metal
ions in a bidentate bridging fashion through the N(1) and N(2) atoms of the heterocycle. The coordination polyhedron of the
metal atoms is a distorted octahedron. The molecular and crystal structures of the complexes [Co3L6(H2O)6](ClO4)6 · 3C2H5OH · 3.75H2O and [M3L6(H2O)6](ClO4)6 · 6H2O (M = Cu2+ and Ni2+) were determined.
Content Type Journal Article
Pages 353-362
DOI 10.1134/S1070328412050065
Authors
E. V. Lider, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
E. V. Peresypkina, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
L. G. Lavrenova, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
L. A. Sheludyakova, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
A. I. Smolentsev, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
T. I. Yaroshenko, Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia
V. N. Elokhina, Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia
New oxamido-bridged binuclear CuII-CuII complexes, [Cu(Oxen)Cu(Bipy)2](ClO4)2 (I) and [Cu(Oxen)Cu(4,4′-Bipy)2(H2O)2](ClO4)2 (II) (Oxen is N,N′-bis(2-aminoethyl)oxamide dianion, Bipy = 2,2′-bipyridine, 4,4′-Bipy = 4,4′-bipyridine), have been constructed
and structurally characterized by X-ray crystallography. In these two complexes, each Cu2+ ion is located in a slightly distorted square-pyramidal environment. Complex I is extended to two-dimensional by face-to-face π-π-stacking with a distance of 3.648 II is raised to one-dimensional by face-to-face π-π-stacking and intermolecular H-bonding interaction with distances of 3.651
and 2.767 I is also investigated.
Content Type Journal Article
Pages 342-348
DOI 10.1134/S1070328412050089
Authors
S. Ren, Department of Application Chemistry, College of Science, Tianjin University of Commerce, Tianjin, 300134 P.R. China
F. H. Li, Department of Application Chemistry, College of Science, Tianjin University of Commerce, Tianjin, 300134 P.R. China
S. L. Ma, Department of Application Chemistry, College of Science, Tianjin University of Commerce, Tianjin, 300134 P.R. China
A new coordination polymer, [(CH3)2NH2][Zn(Tci)] · 2.5H2O (I) (H3Tci = tris(2-carboxyethyl)isocyanurate), has been synthesized under solvothermal conditions. X-ray diffraction analysis reveals
that I features a 2D anionic layer structure constructed by Zn(II) paddle-wheel building blocks and Tci linkers. The Zn(II)
paddle-wheel can be viewed as a node, and the network of I can be simplicated as CdI2 net. Hydrogen bond interactions link the adjacent 2D layers to form a 3D supramolecular framework.
Content Type Journal Article
Pages 315-318
DOI 10.1134/S1070328412050090
Authors
S. Sun, College of Chemistry, Liaoning University, Shenyang, 110036 P.R. China
G. X. Zhang, College of Chemistry, Liaoning University, Shenyang, 110036 P.R. China
J. Q. Gao, College of Chemistry, Liaoning University, Shenyang, 110036 P.R. China
Z. B. Han, College of Chemistry, Liaoning University, Shenyang, 110036 P.R. China
Dodecanuclear mixed-ligand complex [(μ2-Hmhp)6Ni12(μ3-OH)4(μ6-O3PPh)4(μ2-Piv)12] · 7.5MeCN · 1.5THF (I · 7.5MeCN · 1.5THF) was synthesized by the reaction of nickel(II) trimethylacetate [Ni9(OH)6(Piv)12(HPiv)4] (Piv− is the pivalate anion) and 6-methyl-2-hydroxypyridine (Hmhp) with phenylphosphonic acid potassium salt (K2O3PPh). The structure of complex I is determined by X-ray diffraction analysis. The geometry of the metal framework of the isolated complex is determined by
the structure forming phosphonate anion.
Content Type Journal Article
Pages 331-336
DOI 10.1134/S1070328412050016
Authors
N. P. Burkovskaya, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991 Russia
M. E. Nikiforova, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991 Russia
M. A. Kiskin, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991 Russia
V. I. Pekhn’o, Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. akademika Palladina 32/34, Kiev, Ukraine
A. A. Sidorov, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991 Russia
V. M. Novotortsev, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991 Russia
I. L. Eremenko, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991 Russia
A new method for the synthesis of heterometallic clusters Os3M is developed. The reactions of hydridocarbonyl cluster (μ-H)2Os3(CO)10 (I) with binuclear carbonyls Co2(CO)8 and Fe2(CO)9 in the presence of 1,4-diazabicyclo[2.2.2]octane (Dabco) afford anionic complexes [Os3Co(CO)13]− (II) and [HOs3Fe(CO)13] (III) with the counterion N2C6H13+. Similar reactions with halide complexes [MCp*Cl2]2 (M = Rh and Ir) yield neutral complexes [Os3M(CO)10(μ-H)(μ-Cl)] (M = Rh(IV) and Ir(V)). The reactions occur rapidly at room temperature with high yields. The newly obtained
clusters are characterized by the data of IR and 1H NMR spectroscopy, elemental analysis, and X-ray diffraction analysis.
Content Type Journal Article
Pages 273-278
DOI 10.1134/S1070328412020042
Authors
V. P. Kirin, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
M. Yu. Afonin, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
A. V. Virovets, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
V. A. Maksakov, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
A novel bimetallic Cr3Yb3 coordination compound containing a 3d-4f heterometallic Cr2Yb3 cationic cluster has been synthesized and structurally characterized. The crystal structure was determined by X-ray analysis.
Results denote that the complex consists of an original [Cr2IIIYb3III]3+ moiety with a trigonal-bipyramidal topology of the [Cr2Yb3(μ-OOCCH3)6(μ-OH)6(H2O)6]3+ core, an isolated [CrIII(CN)6]3− anion, and four molecular neutral 4,4′-bipyridene (Bipy) ligands, namely, [Cr2Yb3(μ-OOCCH3)6(μ-OH)6(H2O)6][Cr(CN)6] · 4Bipy · 13H2O.
Content Type Journal Article
Pages 253-256
DOI 10.1134/S1070328412040070
Authors
S. L. Ma, Department of Application Chemistry, College of Science, Tianjin University of Commerce, Tianjin, 300134 P.R. China
S. Ren, Department of Application Chemistry, College of Science, Tianjin University of Commerce, Tianjin, 300134 P.R. China
The sorption behavior of novel functionalized endoreceptors, halogen (Br, I) derivatives of [4.4]dibenzo-24-crown-8, with
respect to sorption of 34 elements from 1–5 M HNO3 solurions and 29 elements from 1–5 M HCl solutions were studied. The receptors poorly extract elements from nitric acid solutions
but are strong sorbents of some elements from concentrated hydrochloric acid solutions. The highest distribution ratios of
elements (D, cm3/g) for sorption from 5 M HCl were observed for 4′,4″,5″[4.4]dibromodibenzo-24-crown-8: Au (D = 880) > Ga (469) > Sb (70) > Fe (55) > Sn (14.3) > Mo (10.3) > Re (2.9) > Cd (1.4) > Ge (0.61) > In (0.33) ≈ Zn (0.32) ≈
Ni (0.31) > Zr (0.29) ≈ Cr (0.28) > Sr, Tl (0.25) > Be (0.24) > Mn (0.22) ≈ La (0.21) ≈ Ba (0.20) > Ca, K, Mg, Si (< 0.1).
A new way for increasing the sorption properties of dibenzocrown ethers by introducing bromine substituents into the polyether
benzene rings was established. The sorption of elements from concentrated hydrochloric acid solutions follows an anion exchange
mechanism by analogy with extraction of these elements.
Content Type Journal Article
Pages 295-299
DOI 10.1134/S1070328412040112
Authors
V. V. Yakshin, All-Russia Research Institute of Chemical Technology, Kashirskoe sh. 33, Moscow, 115230 Russia
O. M. Vilkova, All-Russia Research Institute of Chemical Technology, Kashirskoe sh. 33, Moscow, 115230 Russia
S. A. Kotlyar, Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Chernomorskaya doroga 86, Odessa, 270080 Ukraine
A. Yu. Tsivadze, Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117071 Russia
Treatment of CrCl3(THF)3 with KPzTp in THF affords of the compound K[Cr(PzTp)Cl3], and the K+ in this complex can be replaced by Et4N+ in CH2Cl2. Well-defined green crystals of [Et4N]r(PzTp)Cl3] (I) suitable for X-ray diffraction are obtained at −20°C. In the anion the metal center shows a distorted octahedral geometry with the tetra(pyrazolyl) borate bonded as three
N-donor tripod ligands and three chloride atoms completing the coordination sphere.
Content Type Journal Article
Pages 249-252
DOI 10.1134/S1070328412040021
Authors
Y. Ding, School of Chemistry and Materials Science, Xiaogan University, Hubei Xiaogan, 432000 P.R.China
C. F. Xia, School of Chemistry and Materials Science, Xiaogan University, Hubei Xiaogan, 432000 P.R.China
Z. J. Ku, School of Chemistry and Materials Science, Xiaogan University, Hubei Xiaogan, 432000 P.R.China
L. Wang, School of Chemistry and Materials Science, Xiaogan University, Hubei Xiaogan, 432000 P.R.China
Heterometallic chloride complexes [Mo5NbI8Cl6]n− (n = 2, 3) are synthesized. The crystal structures of their salts are determined: for (Ph4P)2[Mo5NbI8Cl6] (I), triclinic crystal system, spacegroup P
-
1
, a = 10.9886(6), b = 11.4604(5), c = 13.4343(7) Å, α = 66.124(2), β = 86.892(2), γ = 86.490(2)°, Z = 1, V = 1543.35(13) Å3; and for (4-MePyH)5[Mo5NbI8Cl6]Cl2 (II), monoclinic crystal system, space group C2/m, a = 16.4937(4), b = 14.7335(3), c = 11.6534(3) Å, β = 99.8750(10)°, Z = 2, V = 2789.94(11) Å The geometric parameters of compounds I and II and the conditions for the formation of the complexes with the charges −2 and −3 are discussed.
Content Type Journal Article
Pages 257-263
DOI 10.1134/S1070328412030013
Authors
S. B. Artemkina, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akad. Lavrent’eva 3, Novosibirsk, 630090 Russia
M. S. Tarasenko, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akad. Lavrent’eva 3, Novosibirsk, 630090 Russia
A. V. Virovets, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akad. Lavrent’eva 3, Novosibirsk, 630090 Russia
N. G. Naumov, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akad. Lavrent’eva 3, Novosibirsk, 630090 Russia
The complex [Ag(2-MePyz)ReO4] (I) is synthesized, and its structure is determined. The crystals are monoclinic, space group P 21/c, a = 7.234(1), b = 15.451(1), c = 8.036(3) Å, β = 92.56(1)°, V = 897.3(2) Å3, ρcalcd = 3.347 g/cm3, Z = 4. Structure I consists of cationic polymer chains [Ag(2-MePyz)]∞+. Anions ReO4− are weakly bound to Ag+ (Ag...Oaverage 2.693 Å) and join the latter into a supramolecular framework. The Ag+ ion has a linear coordination (NAgN 177.9(2)°, distances Ag-N 2.223(5) and 2.242(5) Å).
Content Type Journal Article
Pages 245-248
DOI 10.1134/S1070328412040057
Authors
Yu. V. Kokunov, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991 Russia
Yu. E. Gorbunova, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991 Russia
V. V. Kovalev, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991 Russia
Data on the synthesis and the IR spectroscopic and X-ray diffraction analyses of new complexes of yttrium chloride with carbamide
(Ur), [Y(Ur)4(H2O)4]Cl3 (I) and [Y(Ur)6(H2O)2]Cl3 (II), and with acetamide (AA), [Y(AA)5(H2O)2]Cl3 (III), are presented. The coordination of the ligands occurs through the oxygen atoms. For complexes I and II, the coordination polyhedra of the Y atoms are distorted tetragonal antiprisms. For structure III, the coordination polyhedron of the Y atom is a distorted pentagonal bipyramid. The coordination of four Ur molecules in
complex I does not change their planar structure, and two Ur molecules in structure II have the dihedral angle N-C(O)-N different from 180°. The chloride ions are in the external sphere. Many hydrogen bonds are
observed in the structures of complexes I–III.
Content Type Journal Article
Pages 240-244
DOI 10.1134/S107032841204001X
Authors
L. Yu. Alikberova, Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, Russia
D. V. Al’bov, Moscow State University, Leninskie gory, Moscow, 119992 Russia
P. S. Kibal’nikov, Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, Russia
M. G. Zaitseva, Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, Russia
V. V. Kravchenko, Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, Russia
G. A. Fedorova, Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, Russia
N. S. Rukk, Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, Russia
The reaction of Tb(NO3)3 · 6H2O with 1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)-1,3-propanedi-one (HL) and 1,10-phenanthroline (Phen) in the presence of NaOH in a water-alcohol medium afforded
the neutral complex [Tb(L)3(Phen)] (I). The unstable adduct [Tb(L)3(Phen)] · 0.4 MeCN (II), whose structure is studied by X-ray diffraction analysis, is obtained from an acetonitrile solution. The crystals of compound
II at 100 K are triclinic, a = 11.2508(13), b = 11.4246(14), c = 22.486(3) Å, α = 96.522(2)°, β = 91.578(2)°, γ = 110.073(2)°, V = 2690.3(5) Å3, space group P
-
1
, Z= 2, R = 0.0433. The complex is characterized by the green luminescence (λexc = 380 nm, λem = 550 nm).
Content Type Journal Article
Pages 300-304
DOI 10.1134/S1070328412040100
Authors
I. V. Taidakov, Peoples Friendship University, ul. Miklukho-Maklaya 6, Moscow, Russia
B. E. Zaitsev, Peoples Friendship University, ul. Miklukho-Maklaya 6, Moscow, Russia
A. N. Lobanov, Lebedev Physical Institute, Russian Academy of Sciences, Leninskii pr. 53, Moscow, 119991 Russia
A. G. Vitukhnovskii, Lebedev Physical Institute, Russian Academy of Sciences, Leninskii pr. 53, Moscow, 119991 Russia
Z. A. Starikova, Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991 Russia
A new coordination polymer [Gd(Oba)(Ox)0.5(H2O)2]n (I) (H2Oba = 4,4′-oxybis(benzoic acid), H2Ox = oxalic acid) has been synthesized by hydrothermal reactions and characterized by elemental analysis and single-crystal
X-ray diffraction. In I, two Gd3+ ions are bridged by Oba ligands to form 1D ribbon chains, which are further connected by Ox ligands, generating a 2D layer
structure.
Content Type Journal Article
Pages 305-308
DOI 10.1134/S107032841202008X
Authors
S. Sun, College of Chemistry, Liaoning University, Shenyang, 110036 P.R. China
M. Y. Zhang, College of Chemistry, Liaoning University, Shenyang, 110036 P.R. China
G. X. Zhang, College of Chemistry, Liaoning University, Shenyang, 110036 P.R. China
Z. B. Han, College of Chemistry, Liaoning University, Shenyang, 110036 P.R. China
A new coordination polymer [Cu(H2Tci)2(Bipy)(H2O)] · 2H2O (I) (H3Tci = tris(2-carboxyethyl)isocyanurate, Bipy = 4,4′-bipyridine) has been synthesized and characterized by elemental analysis,
IR, and X-ray single-crystal diffraction. The X-ray diffraction analysis reveals that I (C34H42CuN8O21) crystallizes in the monoclinic crystal system, space group P21/c. In I, the metal centers are linked by Bipy ligands to generate an infinite linear chain and the H2Tci ligands adopt monodentate coordination mode to graft the linear chain. The adjacent chains are linked by hydrogen bonds
to form a three-dimensional supramolecular framework.
Content Type Journal Article
Pages 279-283
DOI 10.1134/S1070328412040124
Authors
M. Y. Zhang, College of Chemistry, Liaoning University, Shenyang, 110036 PR. China
G. X. Zhang, College of Chemistry, Liaoning University, Shenyang, 110036 PR. China
J. Q. Gao, College of Chemistry, Liaoning University, Shenyang, 110036 PR. China
Z. B. Han, College of Chemistry, Liaoning University, Shenyang, 110036 PR. China
Complexation in the systems Pd(II)-Cl−-HA-H2Glu (HA is the l- or d-conformer of 2-methylamino-1-phenylpropanol; H2Glu is glutamic acid) was studied using pH-metric titration, electronic absorption spectroscopy, and quantum-chemical modeling.
It was found that the ratio of the complex species largely depends on pH and the amine, the crucial factor being stabilization
of the structures by hydrogen bonding. This provides explanation to the previous data on the different radioprotective activities
of the complexes (H2A)2[PdCl4] containing the l- and d-conformers of the ligand HA.
Content Type Journal Article
Pages 233-239
DOI 10.1134/S1070328412020029
Authors
I. A. Efimenko, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
N. A. Dobrynina, Moscow State University, Moscow, Russia
O. N. Shishilov, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
N. A. Ivanova, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
O. S. Erofeeva, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
A series of new binuclear bis(catecholate) antimony(V) complexes based on 1,1′-spirobis[3,3-dimethylindanequinone-5,6] with
various substituents at the central antimony atoms, R3Sb(Cat-Spiro-Cat)SbR3 (I–IV) and R3Sb(CatBr-Spiro-BrCat)SbR3 (V–VIII) (R = p-fluorophenyl, phenyl, p-tolyl, and ethyl), were synthesized. Spirobis(catecholates) I–III exhibit two one-electron oxidation waves on the cyclic voltammograms, whereas bromo-substituted spirobis(catecholates) V–VII undergo two-electron oxidation immediately at the first stage. The two-electron oxidation of the complexes results in the
loss of one of the organoantimony fragments and the formation of mononuclear catecholate-quinone complexes (Q-Spiro-Cat)SbR3 or (QBr-Spiro-BrCat)SbR3, respectively. An insignificant delocalization of the charge and spin between two redox centers is observed in the complexes.
The nature of substituents at the antimony atom exerts an effect on the values of redox potentials of the complexes: more
donating groups decrease the oxidation potentials of the catecholate fragments and more withdrawing groups increases these
values.
Content Type Journal Article
Pages 284-294
DOI 10.1134/S1070328412040094
Authors
A. I. Poddel’sky, Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhnii Novgorod, 603600 Russia
I. V. Smolyaninov, Southern Research Center, Russian Academy of Sciences, proezd Chekhova 41, Rostov-on-Don, 344006 Russia
N. N. Vavilina, Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhnii Novgorod, 603600 Russia
Yu. A. Kurskii, Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhnii Novgorod, 603600 Russia
N. T. Berberova, Southern Research Center, Russian Academy of Sciences, proezd Chekhova 41, Rostov-on-Don, 344006 Russia
V. K. Cherkasov, Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhnii Novgorod, 603600 Russia
G. A. Abakumov, Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhnii Novgorod, 603600 Russia
The compounds [Ni(H2O)2(En)2][{Ni(En)2}Re6S8(OH)6] · 7H2O (I), [{Cu(En)2}Re6S8(H2O)2(OH)4] · 4H2O (II), and [Ni(H2O)2(En)2]0.5[Re6Se8(H2O)3(OH)3] · 10H2O (III) were synthesized by layering aqueous solutions of Ni(En)2Cl2 or Cu(En)2Cl2 (En is ethylenediamine) onto aqueous solutions of the potassium salts of the corresponding octahedral chalcohydroxo rhenium
cluster complexes [Re6Q8(OH)6]4− (Q = S, Se). The structure of the obtained compounds was determined by X-ray diffraction analysis.
Content Type Journal Article
Pages 264-272
DOI 10.1134/S1070328412030074
Authors
Y. V. Mironov, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
S. S. Yarovoi, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
A. V. Ermolaev, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
K. A. Brylev, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
Five new rhenium(III) complexes of the general formula ReCl2(RFCOCHCORF)(PPh3)(OPPh3), where RF = CF3 (I), C2F5 (II), C3F7 (III), C4F9 (IV), and CF3CFOC3F7 (V), were synthesized. The known rhenium(V) complex ReOCl2(OC2H5)(PPh3)2, which can readily be obtained from metallic rhenium, was used as a precursor. Two polymorphous modifications of compound
I were found and studied by X-ray diffraction analysis. The thermal properties of the synthesized complexes were characterized
by the DTA-TG method.
Content Type Journal Article
Pages 200-206
DOI 10.1134/S1070328412030037
Authors
D. V. Drobot, Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571 Russia
M. A. Kurykin, Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991 Russia
A. I. Irtegov, Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571 Russia
V. N. Khrustalev, Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991 Russia
M. I. Buzin, Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991 Russia
L. V. Gumileva, Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991 Russia
The oxidation of [CpFe(CO)2]2 by RTeBr3 allowed the corresponding organotellurodibromide complexes CpFe(CO)2TeBr2R (R=Ph, cyclo-(C8H12)(OMe). Their structural features (as determined by single-crystal X-ray diffraction analysis) are discussed.
Content Type Journal Article
Pages 219-223
DOI 10.1134/S1070328412020091
Authors
Y. V. Torubaev, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
A. V. Pavlova, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
A. A. Pasynskii, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Reaction of the thiobromide [Mo3S7Br6]2− cluster anion with 5,6-dimethyl-1,10-phenanthroline (Me2Phen) in solution leads to the substitution of two bromide ligands and the subsequent formation of a new mixed-ligand neutral
complex [Mo3S7Br4(Me2Phen)] (I). Reaction of [Mo3S7Br6]2− with 5,6-dimethyl-1,10-phenanthroline in CH2Cl2 followed by treatment of I with Na(Dtc) · 3H2O (Dtc = diethyldithiocarbamate) results in the new mixed-ligand cluster complex [Mo3S7(Dtc)2(Me2Phen)]2+ (IIa). Slow evaporation of the CHCl3 solution of the complex in the presence of PF6− gives crystals of {[Mo3S7(Dtc)2(Me2Phen)]Br}PF6 · 3CHCl3 (II) characterized by X-ray structural analysis. Close contacts S...S result in the formation of cationic dimers {[Mo3S7(Dtc)2(Me2Phen)]2}4+ which form infinite chains through additional Sax...Br contacts. All compounds were characterized by IR, elemental analysis and ESI-MS. Synthesized complexes represent the
first examples of heteroleptic Mo3S7 clusters containing phenanthroline ligands.
Content Type Journal Article
Pages 173-177
DOI 10.1134/S1070328412030050
Authors
A. Gushchin, Departament de Química Física i Analítica, Universitat Jaume I, Castelló de la Plana, 12071 España
R. Llusar, Departament de Química Física i Analítica, Universitat Jaume I, Castelló de la Plana, 12071 España
D. Recatalá, Departament de Química Física i Analítica, Universitat Jaume I, Castelló de la Plana, 12071 España
P. Abramov, Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, 630090 Russia
The quaternary thioselenochloride complex Os2S6Se2Cl8 (I) was obtained by a reaction of OsO4 with a solution of Se in S2Cl2 at 100°C and identified by combination of X-ray diffraction (polycrystalline approach) and cluster framework isolation. A
reaction of complex I with melted 4-cyanopyridine (4-CNPy) at 165°C gave the complex Os2S2Cl4(4-CNPy)4, which confirms the integrity of the binuclear cluster frame-work [Cl2OsS2OsCl2] in complex I.
Content Type Journal Article
Pages 167-172
DOI 10.1134/S1070328412030104
Authors
S. V. Volkov, Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
R. E. Gladyshevskii, Ivan Franko National University, ul. Kirila i Mefodiya 6, Lviv, Ukraine
Yu. V. Mironov, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
P. Yu. Demchenko, Ivan Franko National University, ul. Kirila i Mefodiya 6, Lviv, Ukraine
O. G. Yanko, Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
A. I. Smolentsev, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Z. A. Fokina, Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
L. B. Khar’kova, Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
S. A. Baranets, Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
The results of the studies on the synthesis, structure, and reactivity of heterometal cuboidal clusters of Mo and W, {M3M′(μ−3Q)4}4+ (M = Mo, W; Q = S, Se; M′ = Ni, Pd), published in the last decade by the authors, have been summarized.
Content Type Journal Article
Pages 159-166
DOI 10.1134/S1070328412020030
Authors
R. Hernandez-Molina, Departamento de Química Inorgánica, Universidad de La Laguna, Islas Canarias, España
M. N. Sokolov, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Single-crystals of a new compound W5Br12 · SbBr3 (I) were isolated as a reaction product from the reduction of WBr6 with elemental antimony at 250°C. The crystal structure was determined by single-crystal X-ray diffraction analysis. The
structure contains square-pyramidal tungsten clusters being linked into infinite [(W5Br8i)Br3aBr22/a-a] chains through shared W-Bra-a-W contacts of adjacent clusters. The structure of the adduct I can be viewed as an intercalation compound composed of double-layers
of cluster chains alternating with mono-layers of SbBr3 molecules.
Content Type Journal Article
Pages 178-182
DOI 10.1134/S1070328412020078
Authors
M. Ströbele, Abteilung für Festkörperchemie und Theoretische Anorganische Chemie, Institut für Anorganische Chemie, Eberhard-Karls-Universität Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen, Germany
H. -J. Meyer, Abteilung für Festkörperchemie und Theoretische Anorganische Chemie, Institut für Anorganische Chemie, Eberhard-Karls-Universität Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen, Germany
Reactions of copper(II) carboxylates with dibenzyl ether (DBE) gave binuclear complexes of the formula Cu2(μ-OOCR)4(DBE)2 (R = But, Ph, and CF3). The complexes were characterized by X-ray diffraction. The axial positions in the lantern-type dimer are occupied by the
coordinated DBE molecules. The complexes seem to be analogs of intermediate catalysts for the oxidation of DBE with atmospheric
oxygen in the presence of transition metal complexes. When stored in air, the complex Cu2(μ-OOCPh)4(DBE)2 underwent oxidation into Cu2(μ-OOCPh)4(HOOCPh)2, which was characterized by X-ray diffraction. The geometry of its framework is similar; the structure is stabilized by intramolecular
H bonds between the axially oriented benzoic acid molecules and the adjacent bridging benzoate anions.
Content Type Journal Article
Pages 224-231
DOI 10.1134/S1070328412030086
Authors
S. E. Nefedov, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991 Russia
E. V. Kushan, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991 Russia
M. A. Yakovleva, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991 Russia
D. G. Chikhichin, Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
V. A. Kotseruba, Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
O. A. Levchenko, Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
G. L. Kamalov, Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
Compounds [Ge38.3Sb7.7]I7.44, [Ge38.1P7.9]I8, and [Ge30.5Sn7.7P7.75]I7.88 with the clathrate type-I structure were synthesized. They crystallize in the cubic space group
Pm
-
3
n
with the unit cell parameter a = 10.8592(9), 10.4983(12), and 10.7210(10) Å (Z = 1), respectively. Their crystal structure represents the germanium(tin)-pnictogen framework, capturing the guest iodine
anions in its cavities. All compounds have no vacancies in the host substructure; however, two of them show vacancies in the
guest positions. The atomic distribution over the framework sites is of the most interest as it follows trends associated
with the relative electronegativities of the atoms composing the framework. The results of the band structure calculations
and application of the Zintl counting scheme are also discussed in relation to potential thermoelectric properties.
Content Type Journal Article
Pages 192-199
DOI 10.1134/S1070328412030062
Authors
M. A. Kirsanova, Chemistry Department, Lomonosov Moscow State University, Moscow, 119991 Russia
L. N. Reshetova, Chemistry Department, Lomonosov Moscow State University, Moscow, 119991 Russia
A. V. Olenev, “SineTheta” Ltd., Scientific Park of Lomonosov Moscow State University, Moscow, 119991 Russia
A. V. Shevelkov, Chemistry Department, Lomonosov Moscow State University, Moscow, 119991 Russia
New octahedral anionic heterometal rhenium-osmium cluster complexes [Re5OsSe8(OH)6]3− and [Re4Os2Se8(OH)6]2− were synthesized starting from [Re5OsSe8Cl6]3− and [Re4Os2Se8Cl6]2−, respectively. They were isolated as salts of the compositions Cs3[Re5OsSe8(OH)6] · 11H2O (I), K3[Re5OsSe8(OH)6] · 7H2O (II), and K2[Re4Os2Se8(OH)6] · 3H2O (III). The protonation of the terminal OH ligands of [Re5OsSe8(OH)6]3− in an aqueous solution resulted in crystallization of a neutral complex [Re5OsSe8(H2O)3(OH)3] · 12H2O (IV). The compounds have been characterized by single-crystal X-ray diffraction analysis. The luminescence properties of [Re5OsSe8(OH)6]3− and [Re4Os2Se8(OH)6]2− were studied. In addition, the electronic structures of the complexes were elucidated by DFT calculations.
Content Type Journal Article
Pages 183-191
DOI 10.1134/S1070328412030025
Authors
K. A. Brylev, Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
N. G. Naumov, Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
S. G. Kozlova, Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
M. R. Ryzhikov, Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
S. -J. Kim, Ewha Womans University, Seoul, 120-750 Republic of Korea
N. Kitamura, Department of Chemistry, Graduate School of Science, Hokkaido University, Sapporo, 060-0810 Japan
Four new low melting salts, “Ionic Liquids” consisting of the [CrIII(NCS)4(Phen)]− complex monoanion and imidazolium based cations A, with A = 1-ethyl-3-methylimidazolium (EMIm), 1-butyl-3-methylimidazolium (BMIm), 1,3-dimethyl-2,4,5-triphenylimidazolium (DML),
and 1,2,3,4,5-pentamethyl-imidazolium (PMIm), were investigated. Single-crystal X-ray investigations established the structures
of the four compounds. (EMIm)[Cr(NCS)4(Phen)] (I): triclinic,
P
-
1
, a = 8.1382(6), b = 10.4760(8), c = 16.003(1) Å, α = 90.330(4)°, β = 94.759(4)°, γ = 107.305(4)°, Z = 2, R1(F)/wR2(F2) = 0.0650/0.1770; (BMIm)[Cr(NCS)4(Phen)] (II): triclinic,
P
-
1
, a = 8.5545(4), b = 9.8620(4), c = 16.6762(6) Å, α = 92.503(2)°, β = 97.517(2)°, γ = 91.249(2)°, Z = 2, R1(F)/wR2(F2) = 0.0393/0.0848; (DML)[Cr(NCS)4(Phen)] · C3H6O (III): triclinic,
P
-
1
, a = 11.0475(9), b = 13.589(1), c = 14.582(1) Å, α = 83.013(4)°, β = 87.116(4)°, γ = 70.333(5)°, Z = 2, R1(F)/wR2(F2) = 0.0407/0.1023; (PMIm)[Cr(NCS)4(Phen)] · C3H6O (IV): orthorhombic, Pbca, a = 17.379(1), b = 16.514(1), c = 22.304(1) Å, Z = 8, R1(F)/wR2(F2) = 0.0460/0.1107 (in addition III and IV contain co-crystallized acetone molecules). Each compound was characterized by elemental analysis, NMR, IR, und UV-Vis spectroscopy.
Magnetic properties were derived from NMR investigations (EVANS method). All four compounds are paramagnetic with effective
magnetic moments of spin-only CrIII. Melting points were obtained from DSC measurements. All melting points are higher than required for “Ionic Liquids”, but
nevertheless “low” for molten salts.
Content Type Journal Article
Pages 207-218
DOI 10.1134/S1070328412030098
Authors
T. Peppel, Department of Chemistry, Inorganic Solid State Chemistry, University of Rostock, Rostock, D-18059 Germany
P. Thiele, Department of Chemistry, Inorganic Solid State Chemistry, University of Rostock, Rostock, D-18059 Germany
M. Köckerling, Department of Chemistry, Inorganic Solid State Chemistry, University of Rostock, Rostock, D-18059 Germany
The chain coordination polymers [Na2(μ-H2O)(H2O)CB[5]]Cl2 · 6H2O (I), [Na3(μ-H2O)4(H2O)4(CNPy@CB[6])]Cl3 · 8H2O (II), and [Rb2(μ-H2O)2(CNPy@CB[6])]Cl2 · 8H2O (III) were prepared by heating (110°C) of a mixture of sodium or rubidium chloride, cucurbit[n]uril (CB[n], where n = 5, 6), 4-cyanopyridine, and water. According to X-ray diffraction data, binding of polynuclear cations with CB[n] in I–III occurs through coordination of the oxygen atoms of the cucurbit[n]uril portals to alkali metal atoms. Complexes I–III of the above composition isolated to the solid phase as supramolecular compounds with CB[n] were structurally characterized
for the first time.
Content Type Journal Article
Pages 153-158
DOI 10.1134/S1070328412020054
Authors
E. A. Kovalenko, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
D. Yu. Naumov, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
V. P. Fedin, Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
A. Müller, Fakultät für Chemie, Universität Bielefeld, Bielefeld, Germany
Reactions of N-(2-hydroxy-3,5-R1,R2-benzyl)-4-aminoantipyrines with copper acetate in ethanol gave complexes with Schiff bases (SBs) rather than the expected
complexes with reduced SBs; i.e., the starting ligands undergo oxidative dehydrogenation during the complexation reaction.
The corresponding complexes with reduced SBs were obtained from sodium salts of the ligands and cupric sulfate in aqueous
solutions. Kinetic measurements showed that oxidative dehydrogenation occurs in the heteroleptic complexes Cu(Li)(CH3COO)(X) (LiH are derivatives of N-(2-hydroxy-3,5-R1,R2-benzyl)-4-aminoantipyrines; i = 6–10; X = H2O, CH3OH, CH3CH2OH) but does not occur in the complexes CH3OH, CH3CH2OH. The absence of oxidative dehydrogenation of the ligands in Cu(Li)2 · H2O can be explained by the octahedral environment of the Cu2+ ion and, accordingly, the absence of the coordination site for molecular oxygen. The molecular structures of two Cu(II) complexes
with SBs were determined by X-ray diffraction.
Content Type Journal Article
Pages 126-133
DOI 10.1134/S1070328412010071
Authors
A. A. Medzhidov, Nagiev Institute of Chemical Problems, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan
P. A. Fatullaeva, Nagiev Institute of Chemical Problems, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan
S. M. Peng, Taiwan National University, Taiwan, Taiwan
R. G. Ismaiylov, Nagiev Institute of Chemical Problems, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan
G. H. Lee, Taiwan National University, Taiwan, Taiwan
S. R. Garaeva, Nagiev Institute of Chemical Problems, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan
A novel N4-planar Cu(II) macrocyclic fragment, namely, [CuL](ClO4)2 (I) (L = 4-methyl-1,3,6,8,11,14-hexaazatricyclo[12.2.1.18,11)octadecane has been prepared from a simple template condensation reaction and structurally characterized for the first time.
The complex of I crystallizes in the monoclinic system of space group P21/c with unit cell parameters: a = 17.124(10), b = 9.255(5), c = 14.053(8) Å and β = 111.262(7)°.
Content Type Journal Article
Pages 145-148
DOI 10.1134/S1070328412010101
Authors
S. Ren, Department of Application Chemistry, College of Science, Tianjin University of Commerce, Tianjin, 300134 P.R. China
S. L. Ma, Department of Application Chemistry, College of Science, Tianjin University of Commerce, Tianjin, 300134 P.R. China
The reaction of cyclopentylamine with 2-hydroxy-1-naphthaldehyde and 5-nitrosalicylaldehyde, respectively, in methanol affords
two new Schiff bases, 1-(cyclopentyliminomethyl)naphthalen-2-ol (HL1) and 4-nitro-2-(cyclopentyliminomethyl)phenol (HL2). Two new zinc(II) complexes, [Zn(L1)2] (I) and [Zn(L2)2] (II), derived from the Schiff bases, have been prepared and characterized by single-crystal X-ray diffraction, FT-IR, and elemental
analysis. Complex I crystallizes in the monoclinic space group P21/c with a = 17.834(4), b = 14.738(3), c = 9.868(2) Å, β = 91.20(3)°, V = 2593.1(9) Å3, Z = 4. Complex II crystallizes in the triclinic space group P
-
1
with a = 10.206(1), b = 10.502(1), c = 12.554(1) Å, α = 66.771(2)°, β = 78.133(2)°, γ = 76.292(2)°, V = 1191.8(1) Å3, Z = 2. The Zn atom in each complex is coordinated by two N and two O atoms from two Schiff base ligands, forming a tetrahedral
geometry. The Schiff bases and the complexes were assayed for antibacterial activities.
Content Type Journal Article
Pages 121-125
DOI 10.1134/S1070328412010034
Authors
Y. N. Guo, Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Baoji, 721013 P.R. China
The heterovalent trinuclear cobalt complexes [Co2IIIL4i · CoII(H2O)4] · nXmY (Li are deprotonated Schiff bases derived from substituted salicylaldehydes and β-alanine; i = 1–3) were obtained and characterized. An X-ray diffraction study of the trinuclear cobalt complex with N-(2-carboxyethyl)salicylaldimine
showed that the central Co(II) ion and the terminal Co(III) ions are linked by bridging carboxylate groups. Either terminal
Co(III) atom is coordinated to two ligand molecules. They form an octahedral environment consisting of two azomethine N atoms,
two phenolate O atoms, and two O atoms of two carboxylate groups. The central Co(II) atom is coordinated to four water molecules
and to two O atoms of two bridging carboxylate ligands involved in the coordination sphere of the terminal Co(III) atoms.
Content Type Journal Article
Pages 140-144
DOI 10.1134/S1070328412010022
Authors
S. R. Garaeva, Institute of Chemical Problems, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan
A. A. Medzhidov, Institute of Chemical Problems, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan
O. Beukgunger, Istanbul Technical University, Istanbul, Turkey
A. Aydin, Marmara University, Istanbul, Turkey
B. Yalcin, Marmara University, Istanbul, Turkey
M. G. Abbasov, Institute of Chemical Problems, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan
Two new dioxomolybdenum(VI) complexes, [MoO2(L1)]n · 0.5nCH3OH (I) and [MoO2(L2)(CH3OH)] (II), where L1 and L2 are the dianionic form of N′-[1-(4-diethylamino-2-hydroxyphenyl)methylidene]isonicotinohydrazide and N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide, respectively, were prepared and structurally characterized by physicochemical
and spectroscopic methods and single-crystal X-ray determination. For complex I, a polymeric structure is obtained, which is linked by coordination of the pyridine N atoms to the Mo atoms of other [MoO2(L1)] units. Complex II is a mononuclear molybdenum compound. In both complexes, the Mo atoms are in octahedral coordination. The catalytic properties
of the complexes indicate that they are efficient catalysts for sulfoxidation.
Content Type Journal Article
Pages 92-98
DOI 10.1134/S107032841202011X
Authors
W. X. Xu, College of Chemical Engineering and Pharmacy, Jingchu University of Technology, Jingmen, 448000 P.R. China
W. H. Li, College of Chemical Engineering and Pharmacy, Jingchu University of Technology, Jingmen, 448000 P.R. China
Two nickel(II) complexes [Ni(NIT-l′-MeBzlrn)2(Dca)2] (I, II) (NIT-l′-MeBzIm = 2-{2′-[(l′methyl)benzimidazolyl]}-4,4,5,5-tetramethylimidazoline-l-oxyl-3-oxide) have been prepared and
structurally characterized by single-crystal X-ray diffraction. They are structural epimers. The complexe crystallizes in
monoclinic, space group P21/n, Z = 4. Crystal data: C34H38N14NiO4, Mr = 765.49, a = 15.019(3), b = 18.803(4), c = 15.756(3) Å, β = 109.399(3)°, γ = 90° (I); a = 13.934(3), b = 11.046(2), c = 24.570(5) Å, β = 90.024(2)° (II). The X-ray analysis reveals that Ni2+ ion resides in a distorted octahedral center. The complex was linked by intermolecular hydrogen bonds, resulting in a ID
chain structure for I and a 2D network configuration for II.
Content Type Journal Article
Pages 115-120
DOI 10.1134/S1070328412020066
Authors
G. Liu, Engineering Research Centre for Waste Oil Recovery Technology and Equipment, Ministry of Education, Chongqing Technology and Business University, Chongqing, 400067 P.R. China
B. Chen, Engineering Research Centre for Waste Oil Recovery Technology and Equipment, Ministry of Education, Chongqing Technology and Business University, Chongqing, 400067 P.R. China
J. T. Cheng, Engineering Research Centre for Waste Oil Recovery Technology and Equipment, Ministry of Education, Chongqing Technology and Business University, Chongqing, 400067 P.R. China
The π-complexes [CuCl(C3H5NHC2H4CN)] (I), [(C3H5NH2C2H4CN)Cu2Cl3] (II), [((C3H5)2NHC2H4CN)CuCl2] (III), and [((C3H5)2NHC2H4CN)CuBr2] (IV) are obtained as single crystals by the ac electrochemical synthesis on copper wire electrodes from ethanolic solutions of
3-(allylamino)propanenitrile, 3-(diallylamino)propanenitrile, and CuX2 (X = Cl, Br). Their crystal structures are determined. The crystals of compounds I, III, and IV are monoclinic, space group P21/c, Z = 4. The crystals of compound II are triclinic, space group P
-
1
, Z = 2. The unit cell parameters are a = 11.125(4), b = 8.769(4), c = 8.570(4) Å, β = 90.94(4)°, V = 835.9(6) Å3 (I); a = 6.2566(4), b = 7.5975(6), c = 11.1251(8) Å, α = 90.896(6)°, β = 92.827(5)°, γ = 94.340(5)°, V = 526.57(7) Å3 (II); a = 11.656(4), b = 6.992(4), c = 14.681(5) Å, β = 100.89(4)°, V = 1174.9(9) Å3 (III); a =11.845(4), b = 7.282(4), c=14.855(5) Å, β = 100.37(4)°, V = 1260.4(9) Å3 (IV). The coordination mode of the Cu(I) atom in complex I includes two halogen atoms, the C=C bond, and the secondary amine N atom. The coordination environment in isostructural crystals
of complexes III and IV is formed by the C=C bond and three halogen atoms as in complex II.
Content Type Journal Article
Pages 86-91
DOI 10.1134/S107032841201006X
Authors
M. Yu. Luk’yanov, Ivan Franko National University, ul. Kirilla i Mefodiya 6, Lviv, 79005 Ukraine
A. V. Pavlyuk, Ivan Franko National University, ul. Kirilla i Mefodiya 6, Lviv, 79005 Ukraine
M. G. Mys’kiv, Ivan Franko National University, ul. Kirilla i Mefodiya 6, Lviv, 79005 Ukraine
A new metal-organic coordination polymer Cu3(Mip)4(2,2′-Bipy)2 (I), where H2Mip = 5-methylisophthalic acid, 2,2′-Bipy = 2,2′-bipyridine has been hydrothermally synthesized and characterized by IR, elemental
analysis, single-crystal X-ray diffraction analysis, and powder X-ray diffraction. The X-ray diffraction analysis reveals
that I crystallizes in the triclinic crystal system, space group P
-
1
and exhibits a one-dimensional chain structure, which contains a trinuclear [Cu3(Mip)2(HMip)2(2,2′-Bipy)2] subunit, and the adjacent subunits are bridged by Mip anions into a 1D chain. Unit cell parameters for I: a = 10.239(2), b = 11.249(2), c = 11.971(2) Å, α = 82.01(1)°, β = 65.03(2)°, γ = 84.32(2)°, V = 1236.5(4) Å3, Z = 2.
Content Type Journal Article
Pages 149-152
DOI 10.1134/S1070328411120116
Authors
H. Y. Zhu, School of Chemistry & Resources Environment, Linyi University, Linyi, 276000 P.R. China
J. W. Ji, School of Chemistry & Resources Environment, Linyi University, Linyi, 276000 P.R. China
Y. W. Li, School of Chemistry & Resources Environment, Linyi University, Linyi, 276000 P.R. China
C. W. Li, School of Chemistry & Resources Environment, Linyi University, Linyi, 276000 P.R. China
K. Z. Zhu, School of Chemistry & Resources Environment, Linyi University, Linyi, 276000 P.R. China
Complex [Cu(CN)(NC(CH2)2O(CH2)2O(CH2)2CN))] is obtained by the heating of copper(I) cyanide with 3,3′-[ethane-1,2-diylbis(oxy)]dipropanenitrile (DPN) followed by
slow cooling. The X-ray diffraction analysis shows that the crystals are monoclinic, space group C2/c, a = 12.183(2), b = 10.667(2), c = 8.4700(13) Å, β = 92.444(10)°, V = 1099.7(3) Å3, Z = 4. The structure is built of infinite zigzag fragments [Cu(CN)(DPN)]n. The tetrahedral environment of the copper atom includes two cyano groups of the ligand and two cyano groups of the inorganic
fragment.
Content Type Journal Article
Pages 111-114
DOI 10.1134/S1070328412020108
Authors
A. A. Vakulka, Jozef Stefan Institute, Ljubljana, Slovenia
E. A. Goreshnik, Jozef Stefan Institute, Ljubljana, Slovenia
M. G. Mys’kiv, Franko National University, ul. Kirila i Mefodiya 6, Lviv, 290005 Ukraine
The reactions of Co(II), Ni(II), and Cu(II) chlorides and bromides and their metallic powders with tetrazol-1-yl-tris(hydroxymethyl)methane
(L) afforded new complexes ML2Hal2 · mH2O(M = Co(II) or Ni(II), Hal = Cl−; M = Cu(II), Hal = Cl− or Br−, m = 0; and M = Co(II) or Ni(II), Hal = Br−, m = 2), MLnCl2 (M = Co(II) or Ni(II), n = 2 or 4; M = Cu(II), n = 2), and MLnBr2 · mH2O (M = Ni(II), n = 2, m = 2; M = Cu(II), n = 2, m = 0). The compositions and structures of the synthesized complexes were determined by elemental analysis, IR spectroscopy
(50–4000 cm−1), and X-ray diffraction analysis. The introduction of a bulky substituent into position 1 of the tetrazole cycle was shown
to exert almost no effect on the coordination mode but affected the composition and structure of the complexes.
Content Type Journal Article
Pages 77-85
DOI 10.1134/S1070328412010010
Authors
M. M. Degtyarik, Research Institute of Physicochemical Problems, Belarussian State University, ul. Leningradskaya 14, Minsk, 220080 Belarus
A. S. Lyakhov, Research Institute of Physicochemical Problems, Belarussian State University, ul. Leningradskaya 14, Minsk, 220080 Belarus
O. A. Ivashkevich, Belarussian State University, ul. Leningradskaya 14, Minsk, 220080 Belarus
Yu. V. Grigoriev, Research Institute of Physicochemical Problems, Belarussian State University, ul. Leningradskaya 14, Minsk, 220080 Belarus
A 3d-3d heterometallic coordination polymer, M(Bpp)(BDC) (I) (M = Co and Zn, Bpp = 1,3-bis(4-pyridyl)propane and H2BDC = 1,4-benzenedicarboxylic acid), has been prepared by hydrothermal synthesis and structurally characterized by IR, elemental
analysis, and single-crystal X-ray diffraction. The Co(II) and Zn(II) ions in I are located indisorder with a molar ratio of 0.35: 0.65. Complex I crystallizes in the orthorhombic space group Pbca and displays a two-dimensional 2-fold interpenetrated structure with (4,4) topology. The coexistence of two metal ions in
the structure makes them more thermally stable than thepreviously reported homometallic polymers of Co(II) or Zn(II) ions.
Complex I exhibits weaker antiferromagnetism than the pure Co(II) complex owing to the incorporation of Zn(II).
Content Type Journal Article
Pages 134-139
DOI 10.1134/S1070328412010046
Authors
X. J. Kong, Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, 246003 P.R. China
C. Guo, Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, 246003 P.R. China
G. X. Liu, Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, 246003 P.R. China
Y. Wang, Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, 246003 P.R. China
S. Nishihara, Department of Physical Science, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka, 599-8531 Japan
A new 1D organic-inorganic hybrid monocopper substituted Dawson-type arsenotungstate (H2En)0.5[Cu(En)2]0.5{[Cu(En)2(H2O)]2[Cu(En)2](α1-As2W17CuO61)} · 8H2O (I) has been hydrothermally synthesized by the reaction of Na8[A-α-HAsW9O34] · 11H2O, CuCl2 · 2H2O, YCl3, with enthylenediamine (En) and characterized by elemental analyses, IR spectra, UV spectra, powder X-ray diffraction, thermogravimetric
analysis, as well as single-crystal X-ray diffraction. Single-crystal structural analysis shows that I displays an interesting 1D chain constructed from [α1-As2W17CuO61]8− subunits by means of common oxygen atoms and [Cu(En)2]2+ bridges. It should be noted that the structural transformation of the trivacant Keggin polyoxoanion [A-α-AsW9O34]9− to the monovacant Dawson [α-As2W17O61]10− polyoxoanion was observed. The TG curve of I exhibits three stages of weight loss.
Content Type Journal Article
Pages 99-105
DOI 10.1134/S1070328412010083
Authors
X. R. Pei, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004 P.R. China
Y. Y. Li, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004 P.R. China
D. Y. Shi, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004 P.R. China
J. Luo, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004 P.R. China
L. J. Chen, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004 P.R. China
J. W. Zhao, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004 P.R. China
The structure of bisphenanthrolinium hexachlorotellurate(IV) (C12H9N2)2TeCl6 is determined by X-ray diffraction analysis: a = 7.6619(8), b = 8.0034(8), c = 10.959(1) Å, α = 82.680(2)°, β = 81.379(2)°, γ = 85.569(2)°; space group P
-
1
, Z = 1, and ρcalcd = 1.774 g/cm3. The crystal structure is built of the [TeCl6]2− anions and phenanthrolinium cations. The electronic and geometric aspects determining the spectral luminescence and thermochromic
properties are discussed.
Content Type Journal Article
Pages 106-110
DOI 10.1134/S1070328412020017
Authors
B. V. Bukvetskii, Institute of Chemistry, Far East Branch, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022 Russia
T. V. Sedakova, Institute of Chemistry, Far East Branch, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022 Russia
A. G. Mirochnik, Institute of Chemistry, Far East Branch, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022 Russia
The influence of thio, dithio, and β-substitutions on the electronic structure and photoelectron spectra of zinc(II) acetylacetonate
was studied by the DFT (density functional theory) quantum-chemical method and photoelectron (PE) spectroscopy. The geometry
of the metallocycles, the energies, the composition of the molecular orbitals, and the effective charges on atoms were determined.
The nature of the corresponding PE spectral bands of the Zn bis-β-diketonates was studied. The bands of four complexes were
interpreted. The simulation of the PE spectra with allowance for the Koopmans defect was proposed.
Content Type Journal Article
Pages 36-43
DOI 10.1134/S1070328411120086
Authors
V. I. Vovna, Far East Federal University, ul. Sukhanova 8, Vladivostok, 690600 Russia
V. V. Korochentsev, Far East Federal University, ul. Sukhanova 8, Vladivostok, 690600 Russia
A. A. Dotsenko, Far East Federal University, ul. Sukhanova 8, Vladivostok, 690600 Russia
Two new dioxomolybdenum(VI) complexes, [MoO2(ClHm)(CH3OH)] (I) and [MoO2(Hm)(CH3OH)] (II) with the hydrazone ligands H2ClHm and H2Hm derived from 4-methylbenzohy-drazide with 5-chlorosalicylaldehyde and salicylaldehyde, respectively, have been synthesized
and structurally characterized by physicochemical methods and single-crystal X-ray determination. The crystal of I crystallizes in the triclinic space group
P
-
1
, with a = 7.839(2), b = 9.656(3), c = 11.548(4) Å α = 88.885(3)°, β = 87.454(3)°, γ = 88.996(3)°, V = 873.0(5) Å3, Z = 2, R1 = 0.0292, wR2 = 0.0685, S = 1.092. The crystal of II crystallizes in the triclinic space group
P
-
1
, with a = 7.780(2), b = 10.584(3), c = 10.628(3) Å, α = 91.462(3)°, β = 104.818(3)°, γ = 103.288(3)°, V = 820.1(4) Å3, Z = 2, R1 = 0.0403, wR2 = 0.0784, S = 1.065. An X-ray analysis indicates that the structures of both complexes are similar to each other. The molybdenum atom
in each complex is in an octahedral coordination environment constructed by two oxo groups, an NO2 donor set of the hydrazone ligand, and one methanol O atom.
Content Type Journal Article
Pages 65-70
DOI 10.1134/S1070328411120037
Authors
Y. Lei, School of Chemistry and Environmental Engineering, Chongqing Three Gorges University, Chongqing, 404000 P.R. China
C. Fu, School of Chemistry and Environmental Engineering, Chongqing Three Gorges University, Chongqing, 404000 P.R. China
